留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

珠江三角洲印刷行业VOCs组分排放清单及关键活性组分

杨杨 杨静 尹沙沙 余宇帆 郑君瑜 莫梓伟

杨杨, 杨静, 尹沙沙, 余宇帆, 郑君瑜, 莫梓伟. 珠江三角洲印刷行业VOCs组分排放清单及关键活性组分[J]. 环境科学研究, 2013, 26(3): 326-333.
引用本文: 杨杨, 杨静, 尹沙沙, 余宇帆, 郑君瑜, 莫梓伟. 珠江三角洲印刷行业VOCs组分排放清单及关键活性组分[J]. 环境科学研究, 2013, 26(3): 326-333.
YANG Yang, YANG Jing, YIN Sha-sha, YU Yu-fan, ZHENG Jun-yu, MO Zi-wei. Speciated VOCs Emission Inventory and Key Species from Printing Industry in the Pearl River Delta Region[J]. Research of Environmental Sciences, 2013, 26(3): 326-333.
Citation: YANG Yang, YANG Jing, YIN Sha-sha, YU Yu-fan, ZHENG Jun-yu, MO Zi-wei. Speciated VOCs Emission Inventory and Key Species from Printing Industry in the Pearl River Delta Region[J]. Research of Environmental Sciences, 2013, 26(3): 326-333.

珠江三角洲印刷行业VOCs组分排放清单及关键活性组分

基金项目: 国家自然科学基金-广东省联合基金项目(U1033001);佛山市环境保护局项目(FSHL2011060G)

Speciated VOCs Emission Inventory and Key Species from Printing Industry in the Pearl River Delta Region

  • 摘要: 根据珠江三角洲地区印刷行业活动数据和不锈钢罐采样-气质联用技术,获取了印刷工艺VOCs成分谱,建立了该地区2010年印刷行业VOCs组分排放清单,研究了不同工艺排放的臭氧生成潜势. 结果表明:该地区2010年印刷行业VOCs排放总量达8591.26t,深圳、东莞、佛山排放量较大.凹印是印刷行业主要VOCs排放工艺,排放量达5762.01t;平印和凸印次之,分别为1954.01和37.82t.不同工艺排放的VOCs组分差异较大,平印工艺排放的VOCs成分中异丙醇含量最多(306.58t),其次为正庚烷(115.87t);苯和甲苯是凸印工艺排放的VOCs成分中含量最大的2种化合物,分别达5.58和4.83t;乙酸乙酯是凹印工艺排放的VOCs成分中的首要化合物,达2482.85t.凸印工艺排放的VOCs单位浓度臭氧潜势最大,达1.30μg/m3,平印和凹印较小,分别为0.89和0.72μg/m3,各工艺排放的含氧有机物对臭氧生成潜势的贡献均为最大.

     

  • [1] ZHANG J,WANG T,CHMEIDES W L,et al.Ozone production and hydrocarbon reactivity in Hong Kong,Southern China.Atmospheric Chemistry and Physics,2007,6(5):557-573.
    [2] GENG Fuhai,ZHAO Chunsheng,TANG Xu,et al.Analysis of ozone and VOCs measured in Shanghai:a case study.Atmos Environ,2007,1(5):989-1001.
    [3] XIE Xin,SHAO Min,LIU Ying,et al.Estimate of initial isoprene contribution to ozone formation potential in Beijing,China.Atmos Environ,2008,2(24):6000-6010.
    [4] SONG Yu,DAI Wei,SHAO Min,et al.Comparison of receptor models for source apportionment of volatile organic compounds in Beijing,China.Environ Pollut,2008,6(1):174-183.
    [5] HATIFIELD M L,HUFF HARTZ K E.Secondary organic aerosol from biogenic volatile organic compound mixtures.Atmos Environ,2011,5(13):2145-2340.
    [6] 唐孝炎,张远航,邵敏.大气环境化学.北京:高等教育出版社,2006.
    [7] ATKINSON R.Kinetics and mechanisms of the gas-phase reaction of the hydroxyl radical with organic compounds under atmospheric conditions.Chem Rev,1985,5:69-201.
    [8] SAUNDERS S M,JENKIN M E,DERWENT R G,et al.Protocol for the development of the Master Chemical Mechanism,MCM v3:Part A.tropospheric degradation of non-aromatic volatile organic compounds.Atmos Chem Phys,2003,3:161-180.
    [9] JENKIN M E,SAUNDERS S M,WAGNER V,et al.Protocol for the development of the Master Chemical Mechanism,MCM v3:Part B.tropospheric degradation of aromatic volatile organic compounds.Atmos Chem Phys,2003,3:181-193.
    [10] 洪盛茂,焦荔,何曦,等.杭州典型区域C2-12质量浓度变化及臭氧潜势量分析.环境科学研究,2009,2(8):938-942.
    [11] ODUM J R,JUNGKAMP P W,GRIFFIN R J,et al.Aromatics,reformulated gasoline,and atmospheric organic aerosol formation.Environ Sci Technol,1997,1:1890-1897.
    [12] 苏讯.我国印刷行业2008年统计数据.江苏造纸,2009(2):31.
    [13] 周震.我国印刷业面临的环境污染问题的挑战.今日印刷,2003(6):2-4.
    [14] 陈宝湘.珠三角地区印刷业发展研究.今日印刷,2007(9):85-87.
    [15] VEGA E,MUGICA R C,EDGAR V.Hydrocarbon source apportionment in Mexico City using the chemical mass balance receptor model.Atmos Environ,2000,4(24):4121-4129.
    [16] NA K,KIM Y P,MOON I,et al.Chemical composition of major VOC emission sources in the Seoul.Atmosphere Chemosphere,2004,5(4):585-594.
    [17] WASTON J G,CHOW J C,FUJITA E M.Review of volatile organic compound source apportionment by chemical mass balance.Atmos Environ,2001,5(9):1567-1584.
    [18] WADDEN R A.Source discrimination of short-term hydrocarbon samples measured aloft.Environ Sci Technol,1986,0(5):473-483.
    [19] SCHEFF P A,WADDEN R A.Receptor modeling of volatile organic compounds:1.emisslon inventory and validation.Environ Sci Technol,1993,7(4):617-625.
    [20] 广东省统计局.广东统计年鉴2011.北京:中国统计出版社,2011.
    [21] 中国印刷科学技术研究社,《印刷技术》出版社.印刷60年印迹.印刷技术,2011(B04):86-101.
    [22] 广东环境保护工程职业学院,华南理工大学环境学院.佛山市大气污染源排放系数研究与排放量调查二期.佛山:佛山环境保护局,2011.
    [23] DUAN Jingchun,TAN Jiha,YANG Liu,et al.Concentration,sources and ozone formation potential of volatile organic compounds(VOCs)during ozone episode in Beijing .Atmos Res,2008,8(1):25-35.
    [24] MARTIEN P T,HARLEY R A,MIFFORD J B.Evaluation of incremental reactivity and its uncertainty in Southern California.Environ Sci Technol,2003,7(8):1598-1608.
    [25] CATER W P L.Development of ozone reactivity scales for volatile organic compounds .J Air Waste Manage Assoc,1994,4(7):881-899.
    [26] 余宇帆,卢清,郑君瑜,等.珠三角地区重点VOC排放行业的排放清单.中国环境科学,2011,1(2):195-201.
    [27] 蔺建明.严格控制润版液浓度保证印刷生产高效运行.印刷技术,2011(2):52-53.
    [28] YUAN Bin,SHAO Min,LU Siha,et al.Source profiles of volatile organic compounds associated with solvent use in Beijing.Atmos Environ,2010,4(15):1919-1926.
    [29] 无帮勇,邓蓓.日本油墨的VOCs排放问题及相应对策.印刷杂志,2006(4):72-73.
    [30] 吴田骅.凹印油墨的原料成分.印刷杂志,2003(7):15-16.
    [31] 钟流举,郑君瑜,雷国强,等.大气污染物排放清单不确定性定量分析方法与案例研究.环境科学研究,2007,0(4):15-16.
    [32] SINGH H B,KANAKLDOU M,CRUTZEN P J,et al.High concentration and photochemical fate of oxygenated hydrocarbons in the global troposphere .Nature,1995,8:50-54.
  • 加载中
计量
  • 文章访问数:  2469
  • HTML全文浏览量:  19
  • PDF下载量:  613
  • 被引次数: 0
出版历程
  • 收稿日期:  2012-09-27
  • 修回日期:  2013-01-12
  • 刊出日期:  2013-03-25

目录

    /

    返回文章
    返回