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MOFs凝胶膜片微固相萃取-气相色谱法测定水样中多溴联苯醚

王林 张超艳 周友亚 颜增光 谢亚勃 李建荣 李发生

王林, 张超艳, 周友亚, 颜增光, 谢亚勃, 李建荣, 李发生. MOFs凝胶膜片微固相萃取-气相色谱法测定水样中多溴联苯醚[J]. 环境科学研究, 2013, 26(4): 446-451.
引用本文: 王林, 张超艳, 周友亚, 颜增光, 谢亚勃, 李建荣, 李发生. MOFs凝胶膜片微固相萃取-气相色谱法测定水样中多溴联苯醚[J]. 环境科学研究, 2013, 26(4): 446-451.
WANG Lin, ZHANG Chao-yan, ZHOU You-ya, YAN Zeng-guang, XIE Ya-bo, LI Jian-rong, LI Fa-sheng. MOFs-Gel-Membrane-Based Micro-Solid-Phase Extraction Coupled with Gas Chromatography for Determination of Polybrominated Diphenyl Ethers in Water[J]. Research of Environmental Sciences, 2013, 26(4): 446-451.
Citation: WANG Lin, ZHANG Chao-yan, ZHOU You-ya, YAN Zeng-guang, XIE Ya-bo, LI Jian-rong, LI Fa-sheng. MOFs-Gel-Membrane-Based Micro-Solid-Phase Extraction Coupled with Gas Chromatography for Determination of Polybrominated Diphenyl Ethers in Water[J]. Research of Environmental Sciences, 2013, 26(4): 446-451.

MOFs凝胶膜片微固相萃取-气相色谱法测定水样中多溴联苯醚

基金项目: 国家自然科学基金项目(21075114); 国家环境保护公益性行业科研专项(201009015,2)

MOFs-Gel-Membrane-Based Micro-Solid-Phase Extraction Coupled with Gas Chromatography for Determination of Polybrominated Diphenyl Ethers in Water

  • 摘要: 为实现对环境水样中污染物PBDEs(多溴联苯醚)的预富集和分析,利用溶胶-凝胶法制取了一种MOFs(金属有机骨架材料)凝胶膜片微固相萃取装置,结合GC-ECD(气相色谱-电子捕获检测器)检测方法测定环境水样中的7种PBDEs,考察了MOFs用量、萃取温度、萃取时间和解吸时间对于萃取效果的影响. 结果表明,在MOFs用量为4mg、萃取温度为70℃、萃取时间为50min、解吸时间为15min的条件下,7种PBDEs单体的加标回收率为74.9%~98.1%,相对标准偏差为3.3%~5.7%,方法检出限均小于4.7ng/L.

     

  • [1] BESIS A,SAMARA C.Polybrominated diphenyl ethers (PBDEs) in the indoor and outdoor environments:a review on occurrence and human exposure.Environ Pollut,2012,9:217.
    [2] KRL S, ZABIEGALA B,NAMISNIK J.PBDEs in environmental samples:sampling and analysis.Talanta,2012,3:1-17.
    [3] 刘汉霞,张庆华,江桂斌,等.多溴联苯醚及其环境问题.化学进展,2005,7(3):554-562.
    [4] MCDONALD T A.A perspective on the potential health risks of PBDEs.Chemosphere,2002,6(5):745-755.
    [5] QIU Xinhua,ZHU Tong,HU Jianxin.Polybrominated diphenyl ethers (PBDEs) and other flame retardants in the atmosphere and water from Taihu Lake, East China.Chemosphere,2010,0(10):1207-1212.
    [6] CHEN D,BI X H,LIU M,et al.Phase partitioning, concentration variation and risk assessment of polybrominated diphenyl ethers (PBDEs) in the atmosphere of an e-waste recycling site.Chemosphere,2011,2(9):1246-1252.
    [7] FREDERIKSEN M,VORKAMP K,THOMESN M,et al.Human internal and external exposure to PBDEs:a review of levels and sources.Int J Hyg Environ Health,2009,2(2):109-134.
    [8] MAN Y B,LOPEZ B N,WANG H S,et al.Cancer risk assessment of polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) in former agricultural soils of Hong Kong.J Hazard Mater,2011,5:92-99.
    [9] SUDARYANTO A,KAJIWARA N,TAKAHASHI S,et al.Geographical distribution and accumulation features of PBDEs in human breast milk from Indonesia.Environ Pollut,2008,1(1):130-138.
    [10] US EPA.Method 1614brominated diphenyl ethers in water soil,sediment and tissue by HRGC/HRMS.Washington DC:Office of Water and Office of Science and Technology Engineering and Analysis Division,1999.
    [11] ALLCHIN C R,LAW R J,MORRIS S.Polybrominated diphenylethers in sediments and biota downstream of potential sources in the UK.Environ Pollut,1999,5(2):197-207.
    [12] CAL D,ELJARRAT E,BARCEL D.Determination of 39polybrominated diphenyl ether congeners in sediment samples using fast selective Pressurized liquid extraction and Purification.J Chromatogr A,2003,1(1/2):165-173.
    [13] SNCHEZ-BRUNETE C,MIGUEL E,TADEO J L.Determination of polybrominated diphenyl ethers in soil by ultrasonic assisted extraction and gas chromatography mass spectrometry.Talanta,2006,0(5):1051-1056.
    [14] BAYEN S,LEE H K,OBBARD J P.Determination of Polybrominated diphenyl ethers in marine biological tissues using microwave-assisted extraction.J Chromatogr A,2004,5(2):291-294.
    [15] ZHANG Z,RHIND S M.Optimized determination of polybrominated diphenyl ethers and polychlorinated biphenyls in sheep serum by solid-phase extraction-gas chromatography-mass spectrometry.Talanta,2011,4(2):487-493.
    [16] VILAPLANA F,CARLSSON P,RIBES-GEUS A,et al.Analysis of brominated flame retardants in styrenic polymers:comparison of the extraction efficiency of ultrasonication, microwave-assisted extraction and pressurised liquid extraction.J chromatogr A,2008,6/1197(4):139-146.
    [17] VILAPLANA F,RIBES-GREUS A,KARLSSON P.Microwave-assisted extraction for qualitative and quantitative determination of brominated flame retardants in styrenic plastic fractions from waste electrical and electronic equipment (WEEE).Talanta,2009,8(1):33-39.
    [18] BASHEER C,ALNEDHARY A A,MADHAVA B S,et al.Development and application of porous membrane-protected carbon nanotube micro-solid-phase extraction combined with gas chromatography/mass spectrometry.Anal Chem,2006,8(8):2853-2858.
    [19] BASHEER C,CHONG H G,HII T M,et al.Application of porous membrane-protected micro-solid-phase extraction combined with HPLC for the analysis of acidic drugs in wastewater.Anal Chem,2007,9(17):6845-6850.
    [20] SERGI M,COMPAGNONE D,CURINI R,et al.Micro-solid phase extraction coupled with high-performance liquid chromatography-tandem mass spectrometry for the determination of stimulants, hallucinogens, ketamine and phencyclidine in oral fluids.Anal Chim Acta,2010,5(2):132-137.
    [21] HUANG J G,LIU J J,ZHANG C,et al.Determination of sulfonamides in food samples by membrane-protected micro-solid phase extraction coupled with high performance liquid chromatography.J Chromatogr A,2012,9:211-216.
    [22] LEE T P,SAAD B,KHAYOON W S,et al.Molecularly imprinted polymer as sorbent in micro-solid phase extraction of ochratoxin A in coffee, grape juice and urine.Talanta,2012,8:129-135.
    [23] 李可及,周友亚,李发生,等.异烟酸铜磁力搅拌微固相萃取-气相色谱法测定土壤中多环芳烃.环境科学研究,2010,3(2):198-202.
    [24] ZHOU Y Y,ZHANG C Y,YAN Z Z,et al.The use of copper(Ⅱ) isonicotinate-based micro-solid-phase extraction for the analysis of polybrominated diphenyl ethers in soils.Anal Chim Acta,2012,7:36-41.
    [25] ZHOU Y Y,YAN X P,KIM K N,et al.Exploration of coordination polymer as sorbent for flow injection solid-phase extraction on-line coupled with high-performance liquid chromatography for determination of polycyclic aromatic hydrocarbons in environmental materials.J Chromatogr A,2011,6(1/2):172-178.
    [26] GU Z Y,WANG G,YAN X P.MOF-5metal-organic framework as sorbent for in-field sampling and preconcentration in combination with thermal desorption GC/MS for determination of atmospheric formaldehyde.Anal Chem,2010,2(4):1365.
    [27] CUI X Y,GU Z Y,JIANG D Q,et al.In situ hydrothermal growth of metal-organic framework 199films on stainless steel fibers for solid-phase microextraction of gaseous benzene homologues.Anal Chem,2009,1(23):9771-9777.
    [28] GU Zhiyuan,CHEN Yingjun,JIANG Junqing,et al.Metal-organic frameworks for efficient enrichment of peptides with simultaneous exclusion of proteins from complex biological samples.Chem Commun,2011,7:4787-4789.
    [29] CARVALHO P H V,BARRETO A S,RODRIGUES M O,et al.Two-dimensional coordination polymer matrix for solid-phase extraction of pesticide residues from plant cordia salicifolia.J Sep Sci,2009,2(12):2132-2138.
    [30] BARRETO A S,ROGRIO L S,SILVA S C G S,et al.Potential of a metal-organic framework as a new material for solid-phase extraction of pesticides from lettuce (lactuca sativa) with analysis by gas chromatography-mass spectrometry.J Sep Sci,2010,3(23/24):3811-3816.
    [31] GE D,LEE H K.Water stability of zeolite imidazolate framework 8and application to porous membrane-protected micro-solid-phase extraction of polycyclic aromatic hydrocarbons from environmental water samples.J Chromatogr A,2011,8(47):8490-8495.
    [32] 魏文英,方键,孔海宁,等.金属有机骨架材料的合成及应用.化学进展,2005,7(6):1110.
    [33] XIE Y B,GAO Q,ZHANG C Y,et al.Two three-dimensional silver(Ⅰ) coordination architectures with pyridine-3,5-dicarboxylate:luminescence and structural dependence on preparing conditions.J Solid State Chem,2009,2(7):1761-1766.
    [34] 许多慧,盛小利,芦昌盛,等.铜(Ⅱ)-二硫烯平面型混配配合物的合成、结构与性质.无机化学学报,2012,8(5):890-891.
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出版历程
  • 收稿日期:  2012-12-07
  • 修回日期:  2013-02-17
  • 刊出日期:  2013-04-25

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