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零价铁PRB技术在地下水原位修复中的研究进展

刘 翔 唐翠梅 陆兆华 卢 欣 李 淼

刘 翔, 唐翠梅, 陆兆华, 卢 欣, 李 淼. 零价铁PRB技术在地下水原位修复中的研究进展[J]. 环境科学研究, 2013, 26(12): 1309-1315.
引用本文: 刘 翔, 唐翠梅, 陆兆华, 卢 欣, 李 淼. 零价铁PRB技术在地下水原位修复中的研究进展[J]. 环境科学研究, 2013, 26(12): 1309-1315.
LIU Xiang, TANG Cui-mei, LU Zhao-hua, LU Xin, LI Miao. Progress of Fe0-PRB in Remediation of Contaminated Groundwater[J]. Research of Environmental Sciences, 2013, 26(12): 1309-1315.
Citation: LIU Xiang, TANG Cui-mei, LU Zhao-hua, LU Xin, LI Miao. Progress of Fe0-PRB in Remediation of Contaminated Groundwater[J]. Research of Environmental Sciences, 2013, 26(12): 1309-1315.

零价铁PRB技术在地下水原位修复中的研究进展

基金项目: 国家水体污染控制与治理科技重大专项(2012ZX07301001)

Progress of Fe0-PRB in Remediation of Contaminated Groundwater

  • 摘要: PRB(可渗透反应墙)是地下水治理中新型的原位修复技术,具有成本低、处理效果好、对环境干扰小等优点,已逐渐应用到实际. 原位修复技术中PRB根据结构的不同可分为单处理系统PRB和多单元处理系统PRB,单处理系统PRB适用于单一污染物、污染浓度较低、污染羽规模较小的场地,多单元系统用于污染场地较复杂、污染种类较多的场地. 零价铁PRB去除地下水中无机污染物及有机组分的反应机理主要是氧化还原反应和还原性脱卤反应. 实际场地PRB的运行中存在的主要问题是零价铁钝化及PRB堵塞,现阶段的解决方法主要包括超声、电化学等,但为了提高PRB技术的实用性,铁材料的解钝化技术、实际场地PRB的设计与安装、PRB体系的长期运行及服务期满后的处置均需进一步的研究探索.

     

  • [1] US EPA.Evaluation of groundwater extraction remedies,EPA office of emergency and remedial responses.Washington DC:US EPA,1989.
    [2] MARTIN T A,KEMPTON J H.In situ stabilization of metal-contaminated groundwater by hydrous ferric oxide:an experimental and modeling investigation.Environ Sci Technol,2000,4(15):3229-3234.
    [3] PHILLIPS D H.Permeable reactive barriers:a sustainable technology for cleaning contaminated groundwater in developing countries.Desalination,2009,8(1/2/3):352-359.
    [4] KANG Seunghee,CHOI Wonyong.Oxidative degradation of organic compounds using zero-valent iron in the presence of natural organic matter serving as an electron shuttle.Environ Sci Technol,2009,3(3):878-883.
    [5] VOGAN J L,FOCHT R M,CLARK D K,et al.Performance evaluation of a permeable reactive barrier for remediation of dissolved chlorinated solvents in groundwater.J Hazard Mater,1999,8(1/2):97-108.
    [6] LI Zhirong,YUAN Songhu,WAN Jinzhong,et al.A combination of electrokinetics and Pd/Fe PRB for the remediation of pentachlorophenol-contaminated soil.Journal of Contaminant Hydrology,2011,4(1/2/3/4):99-107.
    [7] NATALE F D, NATALE M D,GRECO R,et al.Groundwater protection from cadmium contamination by permeable reactive barriers.J Hazard Mater,2008,0(2/3):428-434.
    [8] ALOWITZ M J,SCHIERER M M.Kinetics of nitrate, nitrite, and Cr(Ⅵ) reduction by iron metal.Environ Sci Technol,2002,6(3):2002:299-306.
    [9] LIEN H L,WILKIN R T.High-level arsenite removal from groundwater by zero-valent iron.Chemosphere,2005,9(3):377-386.
    [10] BARTON C S,STEWART D I,MORRIS K S,et al.Performance of three resin-based materials for treating uranium-contaminated groundwater within a PRB.J Hazard Mater,2004,6(3):191-204.
    [11] GAVRILESCU M,PAVEL L V,CRETESCU I.Characterization and remediation of soils contaminated with uranium.J Hazard Mater,2009,3(2/3):475-510.
    [12] HENDERSON A D,DEMOND A H.Long-term performance of zero-valent iron permeable reactive barriers:a critical review.Environmental Engineering Science,2007,4(4):401-423.
    [13] VANSTONE N,PRZEPIORA A,VOGAN J,et al.Monitoring trichloroethene remediation at an iron permeable reactive barrier using stable carbon isotopic analysis.Journal of Contaminant Hydrology,2005,8(4):313-325.
    [14] 许光泉,史红伟,何晓文.PRB技术处理污染地下水的试验研究.合肥工业大学学报:自然科学版,2006,3(6):901-905.
    [15] GAVASKAR A R.Design and construction techniques for permeable reactive barriers.J Hazard Mater,1999,8(1/2):41-71.
    [16] PHILLIPS D H,NOOTEN T V,BASTIAENS L,et al.Ten year performance evaluation of a field-scale zero-valent iron permeable reactive barrier installed to remediate trichloroethene contaminated groundwater.Environ Sci Technol,2010,4(10):3861-3869.
    [17] THIRUVENKATACHARI R,VIGNESWARAN S,NAIDU R.Permeable reactive barrier for groundwater remediation.Journal of Industrial and Engineering Chemistry,2008,4(2):145-156.
    [18] 刘凤莲,刘兴荣.零价铁脱除水中六价铬的实验研究.环境与健康杂志,2009,6(2):139-141.
    [19] 李雅,张增强,唐次来,等.Fe0去除地下水中六价铬的研究.中国农业大学学报,2011,6(2):160-164.
    [20] 邱锦安,张澄博,李洪艺,等.PRB在地下水污染修复中的应用与研究进展.广东农业科学,2011(13):144-146.
    [21] KIILERICH O,LARSEN J W,NIELSEN C.Field results from the use of a permeable reactive wall//California Monterey,CA:Second international conference on remediation of chlorinated and recalcitrant compounds,Monterey,2000.
    [22] STEVEN K.Successful remediation of solvent contaminated ground water using a funnel and gate constructed by slurry trench methods[EB/OL].Orlando:University of Florida.2002[2013-04-05].http://clu-in.org/products/tins/tinsone.cfm?id=10379160&query=groundwater&numresults=25&startrow=1901.
    [23] LEE R D,SMYTH J A.Wall-and-curtain for passive collection/treatment of contaminant plumes.Columbus:Battelle Press,1998.
    [24] AJEFFERIS S,NORRIS G H,THOMAS A O.Developments in permeable and low permeability barriers[EB/OL].Washington DC:US EPA RTDF.2001[2013-06-25].http://www.rtdf.org/PUBLIC/permbarr/prbsumms/profile.cfm?mid=85.
    [25] LEE D R,SMYTH D J A,SHIKAZE S G,et al.Wall and Curtain for Passive Collection/Treatment of Contaminant Plumes[EB/OL].Washington DC:US EPA RTDF.2001[2013-06-25].http://www.rtdf.org/PUBLIC/permbarr/prbsumms/profile.cfm?mid=72.
    [26] JEEN S W,GILLHAM R W,PRZEPIORA A.Predictions of long-term performance of granular iron permeable reactive barriers:field-scale evaluation.Journal of Contaminant Hydrology,2011,3(1/2):50-64.
    [27] YOU Y,HAN J,CHIU P C,et al.Removal and inactivation of waterborne viruses using zero-vealentiron.Environ Sci Technol,2005,9(2):9263-9269.
    [28] LI Lin,BENSON C H,LAWSON E M.Impact of mineral fouling on hydraulic behavior of permeable reactive barriers.Ground Water,2005,3(4):582-596.
    [29] O J S,JEEN S W,GILLHAM R W,et al.Effect of initial iron corrosion rate on long-term performance of iron permeable reactive barriers:column experiments and numerical simulation.Journal of Contaminant Hydrology,2009,3(3/4):145-156.
    [30] WILKIN R,SU Chunming,FORD R,et al.Chromium-removal processes during groundwater remediation by a zero-valent iron permeable reactive barrier.Environ Sci Technol,2005,9:4599-4605.
    [31] 顾雪琼,陈维芳.改性活性炭对饮用水中铬酸盐的去除特性研究.水资源与水工程报,2011(2):20-24.
    [32] 骆其金,谌建宇,许振成,等.适用于污染河水修复的可渗透反应墙材料筛选.水处理技术,2010,6(3):55-58.
    [33] 朱文会,董良飞,王兴润,等.Cr(Ⅵ)污染地下水修复的PRB填料实验研究.环境科学,2013,4(7):2711-2718.
    [34] 宁海丽,朱琨.零价铁/天然沸石对氯酚污染地下水的净化效果研究.兰州交通大学学报:自然科学版,2007,6(1):101-104.
    [35] GIBERTA O,POMIERNY S,ROWE I,et al.Selection of organic substrates as potential reactive materials for use in a denitrification permeable reactive barrier(PRB).Bioresource Technology,2008,9(16):7587-7596.
    [36] LAI K C K,LO I M C.Removal of chromium(Ⅵ) by acid-washed zero-valent iron under various groundwater geochemistry conditions.Environ Sci Technol,2008,2(4):1238-1244.
    [37] DRIES J,BASTIAENS L,SPRINGAEL D,et al.Combined removal of chlorinated ethenes and heavy metals by zerovalent iron in batch and continuous flow column systems.Environ Sci Technol,2005,9(21):8460-8465.
    [38] 杜连柱,张兰英,王立东,等.PRB技术对地下水中重金属离子的处理研究.环境污染与防治,2007,2(8):578-582.
    [39] CONCA J L,WRIGHT J.An apatiteⅡ permeable reactive barrier to remediate groundwater containing Zn,Pb and Cd.Applied Geochemistry,2006,1(8):1288-1300.
    [40] HASHIM M A,MUKHOPADHYAY S,SAHU J N,et al.Remediation technologies for heavy metal contaminated groundwater.J Environ Manage,2011,2(10):2355-2388.
    [41] 张瑞华,孙红文.零价铁修复铬污染水体的实验室研究.农业环境科学学报,2004,3(6):1192-1195.
    [42] WEISENER C G,SALE K S,SMYTH D J A,et al.Field Column study using zerovalent iron for mercury removal from contaminated groundwater.Environ Sci Technol,2005,9(16):6306-6312.
    [43] HOSSEINI S M,ATAIE-ASHTIANI B,KHOLGHI M.Nitrate reduction by nano-Fe/Cu particles in packed column.Desalination,2011,6(1/2/3):214-221.
    [44] MOON H S,AHN K H,LEE S,et al.Use of autotrophic sulfur-oxidizers to remove nitrate from bank filtrate in a permeable reactive barrier system.Environ Pollut,2004,9(3):499-507.
    [45] 张增强,唐次来,邵淼,等.Fe0去除地下水中硝酸盐的条件研究.中国农业大学学报,2008,3(6):37-42.
    [46] 孟凡生,王业耀,张星星.零价铁PRB修复硝酸盐和铬复合污染地下水.环境科学研究,2012,5(11):1279-1284.
    [47] SUZUKI T,OYAMA Y,MORIBE M,et al.An electrokinetic/Fe0permeable reactive barrier system forthe treatment of nitrate-contaminated subsurface soils.Water Res,2012,6(3):772-778.
    [48] GUERINA T F,HORNER S,MCGOVERN T,et al.An application of permeable reactive barrier technology to petroleum hydrocarbon contaminated groundwater.Water Res,2002,6(1):15-24.
    [49] EBERT M,KBER R,PARBS A,et al.Assessing degradation rates of chlorinated ethylenes in column experiments with commercial iron materials used in permeable reactive barriers.Environ Sci Technol,2006,0(6),2004-2010.
    [50] 姜永海,张进保,席北斗,等.Fe0还原地下水中2,4-DNT影响因素及产物.环境科学研究,2010,3(12):1541-1545.
    [51] LO I M,LAM C S,LAI K C.Competitive effects of trichloroethylene on Cr(Ⅵ)Removal by zero-valent iron.J Environ Eng,2005,1(11):1598-1606.
    [52] YANG Ji,CAO Limei,GUO Rui,et al.Permeable reactive barrier of surface hydrophobic granular activated carbon coupled with elemental iron for the removal of 2,4-dichlorophenol in water.J Hazard Mater,2010,4(1/2/3):782-787.
    [53] 苏燕,赵勇胜,赵妍,等.工业铁屑(零价铁)还原硝基苯影响因素研究.中国环境科学,2012,2(8):1452-1455.
    [54] 廖娣劼,杨琦,李俊錡.零价铁降解4-氯硝基苯动力学研究.环境科学,2012,3(2):469-476.
    [55] HENDERSON A D,DEMOND A H.Long-term performance of zero-valent iron permeable reactive barriers:a critical review.Environmental Engineering Science,2007,4(4):401-423.
    [56] VESELA L,NEMECEK J,SIGLOVA M,et al.The biofiltration permeable reactive barrier:practicalexperience from synthesia.International Biodeterioration& Biodegradation,2006,8(3/4):224-230.
    [57] 唐次来,朱艳芳,张增强,等.Fe0去除黄土地区土壤水中的硝酸盐.环境科学学报,2007,7(8):1292-1299.
    [58] MORACI N,CALABR P S.Heavy metals removal and hydraulic performance in zero-valent iron/pumice permeable reactive barriers.J Environ Manage,2010,1(11):2336-2341.
    [59] LI Zhaohui,JONES H K,BOWMAN R S,et al.Enhanced reduction of chromate and PCE by palletized surfactant modified zeolite/zero valentiron.Environ Sci Technol,1999,3(23):4326-4330.
    [60] GRAHAM A M,BOUWER E J.Rates of hexavalent chromiumreduction in anoxic estuarinesediments:pH effects and the roleof acid volatile sulfides.Environ Sci Technol,2010,4(1):136-142.
    [61] JEEN S W,GILLHAM R W,PRZEPIORA A.Predictions of long-term performance of granular iron permeable reactivebarriers:field-scale evaluation.Journal of Contaminant Hydrology,2011,3(1/2):50-64.
    [62] PARBS A,EBERT M,DAHMKE A.Long-term effects of dissolved carbonate species on the degradation of trichloroethylene by zerovalent iron.Environ Sci Technol,2007,1(1):291-296.
    [63] KLAUSEN J,VIKESLAND P J,KOHN T,et al.Longevity of granular iron in groundwater treatment processes:solution composition effects on reduction of organohalides and nitroaromaticcompounds.Environ Sci Technol,2003,7(6):1208-1218.
    [64] BAI Zhihui,CHENG Ying,ZHANG Lizhi,et al.Efficient removal of Cr(Ⅵ)from aqueous solution with Fe@Fe2O3core-shell nanowires.Environ Sci Technol,2008,2:6955-6960.
    [65] PONDER S M,DARAB J G,MALLOUK T E.Remediation of Cr(Ⅵ)and Pb(Ⅱ) aqueous solutions using supported,nanoscale zero-valent iron.Environ Sci Technol,2000,4(12):2564-2569.
    [66] WILKIN R T,PULS R W,SEWELL G W.Long-term performance of permeable reactive barriers using zero-valent iron:geochemical and microbiological effects.Ground Water,2003,1(4):493-503.
    [67] UYUSUR B,UNLU K.A laboratory column investigation for the treatment of Cr(Ⅵ)with zero-valent iron.Environmental Engineering Science,2009,6(2):385-396.
    [68] GEIGER C L,CLAUSEN C A,REINHART D R,et al.Using ultrasound for restoring iron activity in permeable reactive barriers.Washington DC:American Chemical Society,2002:286-303.
    [69] LU X,LI M,TANG C,et al.Electro chemical depassivation for recovering Fe0reactivity by Cr(Ⅵ) removal with a permeable reactive barrier system.J Hazard Mater,2012,1(2):355-360.
    [70] YANG Ji,GUO Yuling,XU Decai,et al.A controllable Fe0-C permeable reactive barrier for 1,4-dichlorobenzene dechlorination.Chemical Engineering Journal,2012,3:166-173.
    [71] PULS R W,BLOWES D W,GILLHAM R W.Long-term performance monitoring for a permeable reactive barrier at the U.S.Coast Guard Support Center,Elizabeth City,North Carolina.J Hazard Mater,1999,8(1/2):109-124.
    [72] DAY R S,O''HANNESIN S F,MARSDEN L.Geotechnical techniques for the construction of reactive barriers.J Hazard Mater,1999,7(3):285-297.
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  • 收稿日期:  2013-04-01
  • 修回日期:  2013-08-10
  • 刊出日期:  2013-12-25

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