留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

络合萃取法处理金刚烷胺制药废水

宋永会 魏 健 马印臣 曾 萍

宋永会, 魏 健, 马印臣, 曾 萍. 络合萃取法处理金刚烷胺制药废水[J]. 环境科学研究, 2014, 27(12): 1513-1518.
引用本文: 宋永会, 魏 健, 马印臣, 曾 萍. 络合萃取法处理金刚烷胺制药废水[J]. 环境科学研究, 2014, 27(12): 1513-1518.
SONG Yong-hui, WEI Jian, MA Yin-chen, ZENG Ping. Treatment of Amantadine Pharmaceutical Wastewater by Complexation Extraction[J]. Research of Environmental Sciences, 2014, 27(12): 1513-1518.
Citation: SONG Yong-hui, WEI Jian, MA Yin-chen, ZENG Ping. Treatment of Amantadine Pharmaceutical Wastewater by Complexation Extraction[J]. Research of Environmental Sciences, 2014, 27(12): 1513-1518.

络合萃取法处理金刚烷胺制药废水

基金项目: 国家水体污染控制与治理科技重大专项(2012ZX07202-002,2012ZX07202-005);中法国际合作项目(2010DFB90590-03)

Treatment of Amantadine Pharmaceutical Wastewater by Complexation Extraction

  • 摘要: 采用络合萃取法处理金刚烷胺制药废水,考察了初始pH、络合剂种类、稀释剂配比、油/水相比和反应温度等对废水中金刚烷胺萃取效率的影响,并对萃取剂中金刚烷胺进行了反萃取分离回收. 结果表明:采用V(P204)〔P204为二(2-乙基己基磷酸)〕∶V(正辛醇)为3∶2的复配萃取剂处理金刚烷胺制药废水,在初始pH为8.0、油/水相比为1∶1和温度为25 ℃的条件下,能够去除废水中99.7%以上的金刚烷胺;在反萃取过程中,V(P204)∶V(正辛醇)为1∶4的复配萃取剂可以获得更高的反萃取效率,以1.0 mol/L的HCl溶液为反萃取剂,当油/水相比为1∶1时,可将51.7%的金刚烷胺从萃取剂中反萃分离,回收得到的金刚烷胺盐酸盐溶液可以回用到生产工艺中,P204-正辛醇复配萃取剂可在萃取和反萃取过程中多次重复使用.

     

  • [1] KAKKAR R,RAJU R V S,RAJUPT A H,et al.Amantadine:an antiparkinsonian agent inhibits bovine brain 60 kDa calmodulin-dependent cyclic nucleotide phosphodiesterase isozyme .Brain Research,1997,9(2):290-294.
    [2] AZUMA T,NAKADA N,YAMASHITA N,et al.Mass balance of anti-influenza drugs discharged into the Yodo River system,Japan,under an influenza outbreak .Chemosphere,2013,3(9):1672-1677.
    [3] 葛孝忠,应黄慧,陈晓,等.金刚烷胺类药物的研究进展.中国医药工业杂志,2003,4(11):583-586.GE Xiaozhong,YING Huanghui,CHEN Xiao,et al.Progress of derivatives of adamantine.Chinese Journal of Pharmaceuticals,2003,4(11):583-586.
    [4] 曾萍,宋永会,DRESELY J,等.金刚烷胺模拟废水Fenton氧化及其中间产物分析.环境工程技术学报,2011,1(6):455-459.ZENG Ping,SONG Yonghui,DRESELY J,et al.Oxidative degradation of simulated amantadine by the Fenton processes and the intermediates analysis.Journal of Environmental Engineering Technology,2011,1(6):455-459.
    [5] 邹倩,傅金祥,姜浩.结晶法处理金刚烷胺废水.辽宁化工,2009,8(12):861-862.ZOU Qian,FU Jinxiang,JIANG Hao.Treatment of amantadine wastewater with the crystallization method.Liaoning Chemical Industry,2009,8(12):861-862.
    [6] 刘晓冉,李金花,周保学,等.铁碳微电解处理中活性炭吸附作用及其影响.环境科学与技术,2011,4(1):128-131.LIU Xiaoran,LI Jinhua,ZHOU Baoxue,et al.Role of activated carbon adsorption in iron-carbon micro-electrolysis process for wastewater treatment.Environmental Science & Technology(China),2011,4(1):128-131.
    [7] KING C J.Handbook of separation process technology:separation process based on reversible chemical complexation .New York:John Wiley & Sons,1987:760-740.
    [8] 许磊,焦庆周,翁世兵,等.萃取-催化氧化处理工业苯酚废水.合肥工业大学学报:自然科学版,2013,6(3):357-360.XU Lei,JIAO Qingzhou,WENG Shibing,et al.Industrial phenol wastewater treatment by extraction-catalytic oxidation process.Journal of Hefei University of Technology,2013,6(3):357-360.
    [9] YANKOV D,MOLINIER J,ALBET J,et al.Lactic acid extraction from aqueous solution with tri-n-octylamine dissolved in decanol and dodecane.Biochemical Engineering Journal,2004,1(1):63-71.
    [10] PROCHAZKA J,HEYBERGER A,VOLAUFOVA E.Extraction equilibrium of dicarboxylic acids with tertiary amine in single and binary diluent.Separation Science & Technology,2005,9(5):1073-1091.
    [11] JIANG H,FANG Y,FU Y,et al.Studies on the extraction of phenol in wastewater.J Hazard Mater,2003,1(2):179-190.
    [12] LI S J,ZHANG L,CHEN H I,et al.Complex extraction and stripping of H acid wastewater .Desalination,2007,6(1/2/3):92-99.
    [13] DONG L,HUANG S,LUO Q,et al.Glutathione extraction and mass transfer in di-(2-ethylhexyl)ammonium phosphate/octanol reverse micelles .Biochemical Engineering Journal,2009,6(2):210-216.
    [14] LEE D W,HONG W H,HWANG K Y,et al.Removal of an organic dye from water using a predispersed solvent extraction .Separation Science and Technology,2000,5(12):1951-1962.
    [15] SHEN S F.Solvent extraction separation of tyramine from simulated alkaloid processing wastewater by Cyanex 923/kerosene .Separation and Purification Technology,2013,3:28-35.
    [16] LI S,ZHUANG J,ZHI T,et al.Combination of complex extraction with reverse osmosis for the treatment of fumaric acid industrial wastewater .Desalination,2008,4(1/2/3):362-369.
    [17] YUAN X,SUN H,GUO D.The removal of COD from coking wastewater using extraction replacement-biodegradation coupling .Desalination,2012,9:45-50.
    [18] 崔节虎,李德亮,郑宾国,等.二(2-乙基己基)磷酸络合萃取邻氨基苯酚的研究.环境化学,2007,6(3):362-365.CUI Jiehu,LI Deliang,ZHENG Binguo,et al.Study on complexation extraction of o-aminophenol with di(2-ethylhexyl)phosphoric acid.Environmental Chemistry,2007,6(3):362-365.
    [19] 李德亮,刘晴,常志显,等.络合萃取分离极性有机物稀溶液的研究进展.化工进展,2009,8(1):13-18.LI Deliang,LIU Qing,CHANG Xianzhi,et al.Development of extraction technique based on chemical complexation for polar organic diluents separation.Chemical Industry and Engineering Progress,2009,8(1):13-18.
    [20] 王叶思,王玉萍,沈燕,等.正辛醇萃取处理硝基C酸废水的研究.南京师范大学学报:工程技术版,2007,7(3):56-59.WANG Yesi,WANG Yuping,SHEN Yan,et al.Study on nitro-C acid wastewater treatment by n-octanol extraction.Journal of Nanjing Normal University:Engineering and Technology Edition,2007,7(3):56-59.
    [21] 王晶仪,吴洪发,鲍妮娜,等.玉米化工醇重组分中有机羧酸络合萃取过程.化工进展,2010,9(6):1023-1026.WANG Jingyi,WU Hongfa,BAO Nina,et al.Complexation extraction of organic acids from corn polyols residue.Chemical Industry and Engineering Progress,2010,9(6):1023-1026.
    [22] 苏海佳,徐丽莲,戴猷元.有机胺类稀溶液的络合萃取.化工学报,1997,8(6):713-720.SU Haijia,XU Lilian,DAI Youyuan.Extraction of organic amines from dilute solution based on chemical complexation.Journal of Chemical Industry and Engineering(China),1997,8(6):713-720.
    [23] JHA A K,JHA M K,KUMARI A,et al.Selective separation and recovery of cobalt from leach liquor of discarded Li-ion batteries using thiophosphinic extractant .Separation and Purification Technology,2013,4:160-166.
    [24] LI S J,CHEN H L,XU J Y,et al.Recovery of fumaric acid from industrial wastewater by chemical extraction and stripping.Separation Science and Technology,2007,2(10):2347-2360.
    [25] 于凤文,姬登祥,艾宁,等.生物柴油萃取高浓度吡啶废水.环境工程学报,2008,2(6):762-764.YU Fengwen,JI Dengxiang,AI Ning,et al.Extraction of high concentrated pyridine in wastewater by bio-diesel.Chinese Journal of Environmental Engineering,2008,2(6):762-764.
    [26] LI S J,ZHANG L,CHEN H L,et al.Complex extraction and stripping of H acid wastewater.Desalination,2007,6(1/2/3):92-99.
    [27] TAN S,XU D,DONG L,et al.Solvent extraction of butyl acetate from lovastatin wastewater using liquid paraffin.Desalination,2012,6:94-98.
    [28] MUTHURAMAN G,TENG T T,LEH C P,et al.Extraction and recovery of methylene blue from industrial wastewater using benzoic acid as an extractant.J Hazard Mater,2009,3(1):363-369.
    [29] XU J Q,DUAN W H,ZHOU X Z,et al.Extraction of phenol in wastewater with annular centrifugal contactors .J Hazard Mater,2006,1(1/2/3):98-102.
    [30] 李振宇,秦炜,杨义燕,等.反应萃取处理染料中间体H酸和DSD酸工业废水.环境科学,2001,2(6):57-60.LI Zhenyu,QIN Wei,YANG Yiyan,et al.Extraction and stripping of H acid and DSD acid wastewater.Environmental Science,2001,2(6):57-60.
  • 加载中
计量
  • 文章访问数:  1973
  • HTML全文浏览量:  13
  • PDF下载量:  1718
  • 被引次数: 0
出版历程
  • 收稿日期:  2013-11-30
  • 修回日期:  2014-05-16
  • 刊出日期:  2014-12-25

目录

    /

    返回文章
    返回