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ABS树脂装置丁二烯聚合工段废水水质表征

冯芦芦 席宏波 周岳溪 杨 琦 宋广清 白兰兰 陈雨卉

冯芦芦, 席宏波, 周岳溪, 杨 琦, 宋广清, 白兰兰, 陈雨卉. ABS树脂装置丁二烯聚合工段废水水质表征[J]. 环境科学研究, 2015, 28(8): 1288-1294.
引用本文: 冯芦芦, 席宏波, 周岳溪, 杨 琦, 宋广清, 白兰兰, 陈雨卉. ABS树脂装置丁二烯聚合工段废水水质表征[J]. 环境科学研究, 2015, 28(8): 1288-1294.
FENG Lulu, XI Hongbo, ZHOU Yuexi, YANG Qi, SONG Guangqing, BAI Lanlan, CHEN Yuhui. Representation of Wastewater from a Section of Butadiene Polymerization by Flocculating Setting Process[J]. Research of Environmental Sciences, 2015, 28(8): 1288-1294.
Citation: FENG Lulu, XI Hongbo, ZHOU Yuexi, YANG Qi, SONG Guangqing, BAI Lanlan, CHEN Yuhui. Representation of Wastewater from a Section of Butadiene Polymerization by Flocculating Setting Process[J]. Research of Environmental Sciences, 2015, 28(8): 1288-1294.

ABS树脂装置丁二烯聚合工段废水水质表征

基金项目: 国家水体污染控制与治理科技重大专项(2012ZX07201-005)

Representation of Wastewater from a Section of Butadiene Polymerization by Flocculating Setting Process

  • 摘要: 为确定某ABS树脂装置丁二烯聚合工段废水水质,特别是特征有机物种类,采用吹扫捕集、静态顶空、固相萃取、固相微萃取和液液萃取等预处理方法与GC/MS(气相色谱/质谱)联用,定性检测出该工段废水中含有16种挥发、半挥发性有机物,主要包括烯烃、苯系物、有机腈、多环芳烃、醚、醇和胺. 废水ρ(SS)(SS为悬浮物)为540.31 mg/L;SS粒径主要分布在0.10~5.00 μm之间,可吸附水中4.83%~33.21%的对二甲苯、乙苯、苯乙烯和1,5-环辛二烯等有机物. 与生活污水不同,该工段废水三维荧光光谱图的荧光区域集中在λExEm(激发波长/发射波长)=205~285 nm/310~360 nm范围内,主要包括λExEm为285 nm/350 nm、260 nm/310 nm、225 nm/345 nm、210 nm/315 nm、230 nm/360 nm的5个荧光峰,由甲苯、靛蓝、苯乙烯、脱氢松香酸、芴、菲等苯系物和多环芳烃类有机物引起. 废水在200~250 nm之间有较强紫外吸收峰,主要由1,3-丁二烯、苯甲醛、苯乙酮、4-苯基-1-环己烯等共轭二烯、不饱和醛、酮和苯系物等有机物引起.

     

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  • 刊出日期:  2015-08-25

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