留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

北京市夏季近地层臭氧对气温的量化响应关系

唐枷榕 田润泽 郭文勇 张众志 徐峻 刘世杰 张树宪 马琳琳 叶子恒 黄荷卉

唐枷榕, 田润泽, 郭文勇, 张众志, 徐峻, 刘世杰, 张树宪, 马琳琳, 叶子恒, 黄荷卉. 北京市夏季近地层臭氧对气温的量化响应关系[J]. 环境科学研究, 2023, 36(5): 904-912. doi: 10.13198/j.issn.1001-6929.2023.02.02
引用本文: 唐枷榕, 田润泽, 郭文勇, 张众志, 徐峻, 刘世杰, 张树宪, 马琳琳, 叶子恒, 黄荷卉. 北京市夏季近地层臭氧对气温的量化响应关系[J]. 环境科学研究, 2023, 36(5): 904-912. doi: 10.13198/j.issn.1001-6929.2023.02.02
TANG Jiarong, TIAN Runze, GUO Wenyong, ZHANG Zhongzhi, XU Jun, LIU Shijie, ZHANG Shuxian, MA Linlin, YE Ziheng, HUANG Hehui. Quantitative Relationship between Near-Surface Ozone and Air Temperature over Beijing Area in Summer[J]. Research of Environmental Sciences, 2023, 36(5): 904-912. doi: 10.13198/j.issn.1001-6929.2023.02.02
Citation: TANG Jiarong, TIAN Runze, GUO Wenyong, ZHANG Zhongzhi, XU Jun, LIU Shijie, ZHANG Shuxian, MA Linlin, YE Ziheng, HUANG Hehui. Quantitative Relationship between Near-Surface Ozone and Air Temperature over Beijing Area in Summer[J]. Research of Environmental Sciences, 2023, 36(5): 904-912. doi: 10.13198/j.issn.1001-6929.2023.02.02

北京市夏季近地层臭氧对气温的量化响应关系

doi: 10.13198/j.issn.1001-6929.2023.02.02
基金项目: 国家自然科学基金项目(No.41575127);国家重点研发计划重点专项(No.2019YFC0214800)
详细信息
    作者简介:

    唐枷榕(1996-),女,广东广州人,jrtang369@163.com

    通讯作者:

    徐峻(1969-),男,北京人,研究员,博士,主要从事区域空气污染研究,xujun@craes.org.cn

  • 中图分类号: X515

Quantitative Relationship between Near-Surface Ozone and Air Temperature over Beijing Area in Summer

Funds: National Natural Science Foundation of China (No.41575127); National Key Research and Development Program of China (No.2019YFC0214800)
  • 摘要: 为研究不同污染水平下,O3浓度对气温升高的敏感程度,利用2018—2020年5—9月近地层O3日最大8 h平均浓度(O3-8 h浓度)和日最高地面气温(Tmax)数据,拟合O3-8 h浓度对Tmax变化的响应斜率(mO3-T),据此对比分析不同类型站点mO3-T的差异和O3污染特征. 结果表明:①各站点O3-8 h浓度均随Tmax升高而增加,在24~36 ℃气温范围内该趋势最明显. ②城区点mO3-T最高,高达10.6 μg/(m3·℃);北部远郊区点和北部背景点mO3-T较低,低至5.2 μg/(m3·℃);近郊区点与城区点的mO3-T相当. ③总体看,北京市mO3-T较高,与O3污染高发地—美国加州南海岸地区20世纪90年代相当,说明目前北京市O3污染水平可能与该时期加州南海岸地区相近. ④周末效应分析表明,北京市北部远郊区点和北部背景点的周末效应均高于主城区点,用mO3-T表征的周末效应能更显著地体现不同区域间的差异. 研究显示,mO3-T能表征北京市的O3污染特征以及目前O3污染治理水平所处阶段.

     

  • 图  1  北京市空气质量监测站点和国家基本气象观测站点位置分布情况

    Figure  1.  Location of air quality monitoring sites and national basic meteorological observation sites in Beijing

    图  2  北京市各类型站点O3-8 h浓度与Tmax的散点图

    注:因版面限制,只展现各类型站点的代表性站点情况.

    Figure  2.  Scatter plot of O3-8 h concentration with Tmax in Beijing

    图  3  北京市各类型站点在1 ℃气温区间内的O3-8 h浓度统计

    注:因版面限制,只展现各类型站点的代表性站点情况.

    Figure  3.  O3-8 h concentration statistics of each Beijing monitoring station by 1 ℃ air temperature segment

    图  4  北京市各站点O3-8 h浓度与Tmax拟合的mO3-T及其相关系数

    注:图例中的蓝色代表城区点,粉色代表郊区点,红色代表背景点,黑色代表交通点.

    Figure  4.  mO3-T fitted with O3-8 h concentration and Tmax and its correlation coefficient at each site in Beijing

    图  5  北京市各站点夏季NO2日均浓度统计

    Figure  5.  Daily NO2 statistic of each Beijing monitoring station in summer

    图  6  北京市各站点mO3-T与美国地区mO3-T的比较

    Figure  6.  mO3-T comparison for each site in Beijing and sites in USA

    图  7  北京市各站点周末与工作日的O3-8 h浓度差及其变幅

    Figure  7.  The difference of O3-8 h concentration between weekdays and weekdays in Beijing and its amplitude of variation

    图  8  北京市各类型站点周末与工作日的mO3-T及其差值的变幅

    注:图例中的粉色代表周末的mO3-T,蓝色代表工作日的mO3-T.

    Figure  8.  mO3-T on weekends and weekdays of sites in Beijing and its magnitude of variation in the difference

    表  1  北京市空气质量监测站点

    Table  1.   Air quality monitoring station in Beijing

    类型站点名称
    城区点 东城东四、东城天坛、西城官园、西城万寿西宫、朝阳奥体中心、朝阳农展馆、海淀万柳、海淀北部新区、丰台花园、丰台云岗、石景山古城
    郊区点 近郊区:房山良乡、大兴黄村镇、亦庄开发区、通州新
    城、顺义新城、昌平镇、门头沟龙泉镇
    远郊区:平谷镇、怀柔镇、密云镇、延庆镇
    背景点 南部背景点:京东南永乐店、京南榆垡、京西南琉璃河
    北部背景点:昌平定陵、京西北八达岭、京东北密云水库、京东东高村
    交通点 前门东大街、永定门内大街、西直门北大街、南三环西路、东四环北路
    下载: 导出CSV
  • [1] 姜华,常宏咪.我国臭氧污染形势分析及成因初探[J].环境科学研究,2021,34(7):1576-1582.

    JIANG H,CHANG H M.Analysis of China's ozone pollution situation,preliminary investigation of causes and prevention and control recommendations[J].Research of Environmental Sciences,2021,34(7):1576-1582.
    [2] 李红,彭良,毕方,等.我国PM2.5与臭氧污染协同控制策略研究[J].环境科学研究,2019,32(10):1763-1778.

    LI H,PENG L,BI F,et al.Strategy of coordinated control of PM2.5 and ozone in China[J].Research of Environmental Sciences,2019,32(10):1763-1778.
    [3] CAMALIER L,COX W,DOLWICK P.The effects of meteorology on ozone in urban areas and their use in assessing ozone trends[J].Atmospheric Environment,2007,41(33):7127-7137. doi: 10.1016/j.atmosenv.2007.04.061
    [4] JACOB D J,WINNER D A.Effect of climate change on air quality[J].Atmospheric Environment,2009,43(1):51-63. doi: 10.1016/j.atmosenv.2008.09.051
    [5] LIN C Y C,JACOB D J,FIORE A M.Trends in exceedances of the ozone air quality standard in the continental United States,1980-1998[J].Atmospheric Environment,2001,35(19):3217-3228. doi: 10.1016/S1352-2310(01)00152-2
    [6] FILLEUL L,CASSADOU S,MÉDINA S,et al.The relation between temperature,ozone,and mortality in nine French cities during the heat wave of 2003[J].Environmental Health Perspectives,2006,114(9):1344-1347. doi: 10.1289/ehp.8328
    [7] LEE J D,LEWIS A C,MONKS P S,et al.Ozone photochemistry and elevated isoprene during the UK heatwave of August 2003[J].Atmospheric Environment,2006,40(39):7598-7613. doi: 10.1016/j.atmosenv.2006.06.057
    [8] TRESSOL M,ORDONEZ C,ZBINDEN R,et al.Air pollution during the 2003 European heat wave as seen by MOZAIC airliners[J].Atmospheric Chemistry and Physics,2008,8(8):2133-2150. doi: 10.5194/acp-8-2133-2008
    [9] PYRGOU A,HADJINICOLAOU P,SANTAMOURIS M.Enhanced near-surface ozone under heatwave conditions in a Mediterranean island[J].Scientific Reports,2018,8:9191. doi: 10.1038/s41598-018-27590-z
    [10] VAROTSOS K V,GIANNAKOPOULOS C,TOMBROU M.Ozone-temperature relationship during the 2003 and 2014 heatwaves in Europe[J].Regional Environmental Change,2019,19(6):1653-1665. doi: 10.1007/s10113-019-01498-4
    [11] 张晓,张艳品,钤伟妙.石家庄市主城区臭氧污染特征及气象成因分析[J].环境科学研究,2021,34(2):245-253.

    ZHANG X,ZHANG Y P,QIAN W M.Characteristics of ozone pollution and its meteorological factors in Shijiazhuang urban area[J].Research of Environmental Sciences,2021,34(2):245-253.
    [12] 赵敏,申恒青,陈天舒,等.黄河三角洲典型城市夏季臭氧污染特征与敏感性分析[J].环境科学研究,2022,35(6):1351-1361.

    ZHAO M,SHEN H Q,CHEN T S,et al.Characteristics and sensitivity analysis of ozone in the representative city of the Yellow River Delta in summer[J].Research of Environmental Sciences,2022,35(6):1351-1361.
    [13] 何国文,吴兑,吴晟,等.嘉兴夏季臭氧污染的近地层垂直变化特征[J].中国环境科学,2020,40(10):4265-4274.

    HE G W,WU D,WU S,et al.Characterizing the near-surface vertical variations of summertime O3 in Jiaxing[J].China Environmental Science,2020,40(10):4265-4274.
    [14] BLOOMER B J,STEHR J W,PIETY C A,et al.Observed relationships of ozone air pollution with temperature and emissions[J].Geophysical Research Letters,2009,36(9):L09803.
    [15] STEINER A L,DAVIS A J,SILLMAN S,et al.Observed suppression of ozone formation at extremely high temperatures due to chemical and biophysical feedbacks[J].Proceedings of the National Academy of Sciences of the United States of America,2010,107(46):19685-19690. doi: 10.1073/pnas.1008336107
    [16] RASMUSSEN D J,FIORE A M,NAIK V,et al.Surface ozone-temperature relationships in the eastern US:a monthly climatology for evaluating chemistry-climate models[J].Atmospheric Environment,2012,47:142-153. doi: 10.1016/j.atmosenv.2011.11.021
    [17] RASMUSSEN D J,HU J L,MAHMUD A,et al.The ozone-climate penalty:past,present,and future[J].Environmental Science & Technology,2013,47(24):14258-14266.
    [18] PUSEDE S E,STEINER A L,COHEN R C.Temperature and recent trends in the chemistry of continental surface ozone[J].Chemical Reviews,2015,115(10):3898-3918. doi: 10.1021/cr5006815
    [19] NINNEMAN M,JAFFE D.Observed relationship between ozone and temperature for urban nonattainment areas in the United States[J].Atmosphere,2021,12(10):1235. doi: 10.3390/atmos12101235
    [20] SILLMAN S,SAMSON P J.Impact of temperature on oxidant photochemistry in urban,polluted rural and remote environments[J].Journal of Geophysical Research,1995,100(D6):11497. doi: 10.1029/94JD02146
    [21] OTERO N,RUST H W,BUTLER T.Temperature dependence of tropospheric ozone under NOx reductions over Germany[J].Atmospheric Environment,2021,253:118334. doi: 10.1016/j.atmosenv.2021.118334
    [22] PUSEDE S E,COHEN R C.On the observed response of ozone to NOx and VOC reactivity reductions in San Joaquin Valley California 1995-present[J].Atmospheric Chemistry and Physics,2012,12(18):8323-8339. doi: 10.5194/acp-12-8323-2012
    [23] PUSEDE S E,GENTNER D R,WOOLDRIDGE P J,et al.On the temperature dependence of organic reactivity,nitrogen oxides,ozone production,and the impact of emission controls in San Joaquin Valley,California[J].Atmospheric Chemistry and Physics,2014,14(7):3373-3395. doi: 10.5194/acp-14-3373-2014
    [24] POLLACK I B,RYERSON T B,TRAINER M,et al.Airborne and ground-based observations of a weekend effect in ozone,precursors,and oxidation products in the California South Coast Air Basin[J].Journal of Geophysical Research:Atmospheres,2012,117(D21):D00V05.
    [25] 黄俊,廖碧婷,吴兑,等.广州近地面臭氧浓度特征及气象影响分析[J].环境科学学报,2018,38(1):23-31. doi: 10.13671/j.hjkxxb.2017.0256

    HUANG J,LIAO B T,WU D,et al.Guangzhou ground level ozone concentration characteristics and associated meteorological factors[J].Acta Scientiae Circumstantiae,2018,38(1):23-31. doi: 10.13671/j.hjkxxb.2017.0256
    [26] 王玫,郑有飞,柳艳菊,等.京津冀臭氧变化特征及与气象要素的关系[J].中国环境科学,2019,39(7):2689-2698.

    WANG M,ZHENG Y F,LIU Y J,et al.Characteristics of ozone and its relationship with meteorological factors in Beijing-Tianjin-Hebei Region[J].China Environmental Science,2019,39(7):2689-2698.
    [27] KARLSSON P E,KLINGBERG J,ENGARDT M,et al.Past,present and future concentrations of ground-level ozone and potential impacts on ecosystems and human health in northern Europe[J].Science of the Total Environment,2017,576:22-35. doi: 10.1016/j.scitotenv.2016.10.061
    [28] GUENTHER A B,ZIMMERMAN P R,HARLEY P C,et al.Isoprene and monoterpene emission rate variability:model evaluations and sensitivity analyses[J].Journal of Geophysical Research,1993,98(D7):12609. doi: 10.1029/93JD00527
    [29] SHEN L,MICKLEY L J,GILLELAND E.Impact of increasing heat waves on U.S.ozone episodes in the 2050s:results from a multimodel analysis using extreme value theory[J].Geophysical Research Letters,2016,43(8):4017-4025. doi: 10.1002/2016GL068432
    [30] 程念亮,李云婷,张大伟,等.2014年北京市城区臭氧超标日浓度特征及与气象条件的关系[J].环境科学,2016,37(6):2041-2051.

    CHENG N L,LI Y T,ZHANG D W,et al.Characteristics of ozone over standard and its relationships with meteorological conditions in Beijing City in 2014[J].Environmental Science,2016,37(6):2041-2051.
    [31] 安俊琳,王跃思,孙扬.气象因素对北京臭氧的影响[J].生态环境学报,2009,18(3):944-951. doi: 10.3969/j.issn.1674-5906.2009.03.027

    AN J L,WANG Y S,SUN Y.Assessment of ozone variations and meteorological effects in Beijing[J].Ecology and Environmental Sciences,2009,18(3):944-951. doi: 10.3969/j.issn.1674-5906.2009.03.027
    [32] BLANCHARD C L,FAIRLEY D.Spatial mapping of VOC and NOx:limitation of ozone formation in Central California[J].Atmospheric Environment,2001,35(22):3861-3873. doi: 10.1016/S1352-2310(01)00153-4
    [33] KERR G H,WAUGH D W,STRODE S A,et al.Disentangling the drivers of the summertime ozone-temperature relationship over the United States[J].Journal of Geophysical Research:Atmospheres,2019,124(19):10503-10524. doi: 10.1029/2019JD030572
    [34] PORTER W C,HEALD C L.The mechanisms and meteorological drivers of the summertime ozone-temperature relationship[J].Atmospheric Chemistry and Physics,2019,19(21):13367-13381. doi: 10.5194/acp-19-13367-2019
    [35] FU T M,ZHENG Y Q,PAULOT F,et al.Positive but variable sensitivity of August surface ozone to large-scale warming in the southeast United States[J].Nature Climate Change,2015,5(5):454-458. doi: 10.1038/nclimate2567
    [36] COATES J,MAR K A,OJHA N,et al.The influence of temperature on ozone production under varying NOx conditions:a modelling study[J].Atmospheric Chemistry and Physics,2016,16(18):11601-11615. doi: 10.5194/acp-16-11601-2016
    [37] MARR L C,HARLEY R A.Spectral analysis of weekday-weekend differences in ambient ozone,nitrogen oxide,and non-methane hydrocarbon time series in California[J].Atmospheric Environment,2002,36(14):2327-2335. doi: 10.1016/S1352-2310(02)00188-7
    [38] ATKINSON-PALOMBO C M,MILLER J A,BALLING R C J.Quantifying the ozone ‘weekend effect’ at various locations in Phoenix,Arizona[J].Atmospheric Environment,2006,40(39):7644-7658. doi: 10.1016/j.atmosenv.2006.05.023
    [39] CLEVELAND W S,GRAEDEL T E,KLEINER B,et al.Sunday and workday variations in photochemical air pollutants in new jersey and New York[J].Science,1974,186(4168):1037-1038. doi: 10.1126/science.186.4168.1037
    [40] LEBRON F.A comparison of weekend-weekday ozone and hydrocarbon concentrations in the Baltimore-Washington metropolitan area[J].Atmospheric Environment,1975,9(9):861-863. doi: 10.1016/0004-6981(75)90046-3
    [41] ELKUS B,WILSON K R.Photochemical air pollution:weekend-weekday differences[J].Atmospheric Environment,1977,11(6):509-515. doi: 10.1016/0004-6981(77)90067-1
    [42] TANG W Y,ZHAO C S,GENG F H,et al.Study of ozone ‘weekend effect’ in Shanghai[J].Science China:Earth Sciences,2008,51(9):1354-1360. doi: 10.1007/s11430-008-0088-2
    [43] WANG Y H,HU B,JI D S,et al.Ozone weekend effects in the Beijing-Tianjin-Hebei metropolitan area,China[J].Atmospheric Chemistry and Physics,2014,14(5):2419-2429. doi: 10.5194/acp-14-2419-2014
    [44] WANG Z S,LI Y T,CHEN T,et al.Ground-level ozone in urban Beijing over a 1-year period:temporal variations and relationship to atmospheric oxidation[J].Atmospheric Research,2015,164/165:110-117. doi: 10.1016/j.atmosres.2015.05.005
    [45] ZHAO X L,ZHOU W Q,HAN L J.Human activities and urban air pollution in Chinese mega city:an insight of ozone weekend effect in Beijing[J].Physics and Chemistry of the Earth,2019,110:109-116. doi: 10.1016/j.pce.2018.11.005
    [46] ZOU Y,CHARLESWORTH E,YIN C Q,et al.The weekday/weekend ozone differences induced by the emissions change during summer and autumn in Guangzhou,China[J].Atmospheric Environment,2019,199:114-126. doi: 10.1016/j.atmosenv.2018.11.019
    [47] FUJITA E M,STOCKWELL W R,CAMPBELL D E,et al.Evolution of the magnitude and spatial extent of the weekend ozone effect in California's south coast air basin,1981-2000[J].Journal of the Air & Waste Management Association,2003,53(7):802-815.
  • 加载中
图(8) / 表(1)
计量
  • 文章访问数:  226
  • HTML全文浏览量:  58
  • PDF下载量:  110
  • 被引次数: 0
出版历程
  • 收稿日期:  2022-10-18
  • 修回日期:  2023-01-13

目录

    /

    返回文章
    返回