氧化铁矿物在微波修复多环芳烃污染土壤中的作用机制
The Mechanism of Iron Oxide Minerals on the Microwave Remediation of Soil Contaminated by Polycyclic Aromatic Hydrocarbons
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摘要: 多环芳烃(PAHs)是焦化污染场地中常见的污染物. 微波修复具有加热均匀、低能耗、耗时短的特点,在土壤修复中有较好的应用前景. 该研究选择氧化铁矿物含量低的污染土壤作为试验对象,分别添加10%的针铁矿、赤铁矿和磁铁矿,对添加前后土壤的吸波性能、升温特性及PAHs去除率进行研究,评价氧化铁矿物在微波修复PAHs污染土壤中的作用. 结果表明:土壤中加入氧化铁矿物能够改善其吸波性能,提高复介电常数、复磁导率的实部值和复磁导率的虚部值,分别最大提高了31.79%、12.24%和73.91%. 氧化铁矿物的加入使得土壤产生自由基,促进土壤极化现象,增强吸波能力. 氧化铁矿物还能够改善土壤的升温特性,当微波功率为600 W,添加了针铁矿、赤铁矿、磁铁矿的土壤所达到的最高温度分别是原土壤的1.23、1.10和1.07倍. 随着温度的升高,PAHs去除率随之升高,分别是原土壤的1.45、1.31和1.48倍. 研究显示,氧化铁矿物的添加能够提高微波修复PAHs的效能.
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关键词:
- 多环芳烃(PAHs) /
- 污染土壤 /
- 氧化铁矿物 /
- 微波修复 /
- 吸波能力
Abstract: Polycyclic aromatic hydrocarbons (PAHs) are the common pollutants in coke pollution sites. Microwave remediation has been widely applied in soil remediation because it has characteristics of homogeneous heating of substance, low energy consumption jointly with short remediation times. In this study, the effect of iron oxide minerals on the microwave remediation of soil contaminated by polycyclic aromatic hydrocarons is evaluated. The contaminated soil with low iron oxide content was selected as the object, and goethite, hematite and magnetite with 10%wt were added, after which the microwave remediation was conducted. The absorbing ability, heating characteristics and removal rate of PAHs in the absence or presence of iron oxide were observed. The results show that the addition of iron oxide mineral in soils can improve the adsorption property. The values of the real complex permittivity and permeability as well as the imaginary permeability are increased by 31.79%、12.24% and 73.91%, respectively. The addition of iron oxide minerals leads to more free radicals in soils and facilitates the polarization of soil, which can enhance the ability of absorption. Iron oxide can also improve the soil heating characteristics. When the microwave power was 600W, the maximum temperature of the soil with goethite, hematite and magnetite added was 1.23, 1.10 and 1.07 times more than that of the original soil, respectively. With the increase of temperature, the removal rates of PAHS were 1.45、1.31 and 1.48 times more than that of the original soil, respectively. The results showed that the addition of iron oxide mineral could improve the efficiency of PAHs microwave remediation.
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