有机污染土壤堆式热脱附过程中热湿迁移实验及数值模拟
Experiment and numerical simulation of heat and moisture migration in thermal desorption process
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摘要: 堆式燃气热脱附技术因其具有二次污染小、污染物去除率高和处理周期短等优势而得到快速发展。土壤中的水分是影响堆体热修复过程中土壤升温的关键因素,然而其热湿迁移机理尚不明晰,工程设计主要依赖于实践经验。本研究以山东某污染场地的砂质壤土开展了堆体热湿迁移实验,结合COMSOL仿真模拟,系统分析了加热过程中土壤温度和湿度在竖直和水平方向上的变化规律。结果表明,热源附近土壤水分呈逐渐升高并出现短暂峰值(高于初始值10.9%)后再下降的趋势,水分峰值随温度提高而升高;热源温度越高,土壤中水汽的对流和扩散作用愈加明显,当热源温度由50℃升高至100℃时,监测点含水量下降由4.5%提升至27.2%,且水汽的浓度扩散机制在水分迁移过程中占主导作用;对于相同热源作用下,初始体积含水量较高的土壤具有相对较高的温度变化,当初始体积含水量由0.07m³/m³升高至0.16m³/m³时,监测点的温度由37.1℃升至40.0℃,且温升过程中对流传热以及热传导的作用越显著,其中多孔基体间的热传导作用占主导作用。该研究结果可为研究堆体热脱附过程中热湿迁移规律提供理论支持。Abstract: ex-situ thermal pile desorption technology has been developed rapidly because of its advantages of less secondary pollution, high pollutant removal rate and short treatment cycle. Soil moisture is the key factor affecting soil temperature rise in the process of pile thermal restoration. However, the mechanism of heat and moisture migration is still unclear, and engineering design mainly depends on practical experience. In this study, the sand loam in a polluted site in Shandong Province was used to carry out the experiment of heat and moisture transfer in heaps. Combined with COMSOL simulation, the variation rules of soil temperature and humidity in vertical and horizontal directions during the heating process were systematically analyzed. The results showed that the soil moisture near the heat source increased gradually and appeared a short peak value (10.9% higher than the initial value) and then decreased. The peak value of soil moisture increased with the increase of temperature; The higher the heat source temperature is, the more obvious the convection and diffusion of water vapor in the soil is. When the heat source temperature rises from 50℃ to 100℃, the water content at the monitoring point decreases from 4.5% to 27.2%, and the concentration diffusion mechanism of water vapor plays a dominant role in the water transfer process; For the same heat source, the soil with higher initial volume water content has relatively higher temperature change. When the initial volume water content changes from 0.07m³/ m³ Raise to 0.16m³/ m³ The temperature of the monitoring point rises from 37.1℃ to 40.0℃, and the convection heat transfer and heat conduction play a more significant role in the temperature rise process, in which the heat conduction between porous substrates plays a dominant role. The research results can provide theoretical support for the study of heat and moisture migration in the process of reactor thermal pile desorption.
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