Volume 36 Issue 1
Jan.  2023
Turn off MathJax
Article Contents
Article Navigation >  Research of Environmental Sciences  > 2023  >  36(1): 44-53
ZHANG Weiqi, XIE Tao, SUN Zhijing, WANG Maolin, CAI Xiyun. Developments of the Method of Microwave Digestion and Flame Atomic Absorption Spectrometry for Determination of Hexavalent Chromium in Soils[J]. Research of Environmental Sciences, 2023, 36(1): 44-53. doi: 10.13198/j.issn.1001-6929.2022.11.27
Citation: ZHANG Weiqi, XIE Tao, SUN Zhijing, WANG Maolin, CAI Xiyun. Developments of the Method of Microwave Digestion and Flame Atomic Absorption Spectrometry for Determination of Hexavalent Chromium in Soils[J]. Research of Environmental Sciences, 2023, 36(1): 44-53. doi: 10.13198/j.issn.1001-6929.2022.11.27
shu

Developments of the Method of Microwave Digestion and Flame Atomic Absorption Spectrometry for Determination of Hexavalent Chromium in Soils

doi: 10.13198/j.issn.1001-6929.2022.11.27
  • 1.

    Dalian Product Quality Inspection and Testing Institute Co., Ltd., Dalian 116021, China

  • 2.

    Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China

Funds:  National Key Research and Development Program of China (No. 2019YFC1803803)
  • Received Date: 2022-09-08
  • Rev Recd Date: 2022-11-15
    Abstract
  • The alkali solution extraction method is commonly used to extract hexavalent chromium in soils, according to the standard for Alkali Solution Extraction-Flame Atomic Absorption Spectrophotometry (HJ 1082-2019). This method has some problems for the detection of batch soils, including long extraction time, high reagent consumption, and large temperature variations. Therefore, it is highly desirable to develop a determination method of hexavalent chromium in soils with high efficiency and accuracy for risk assessments and remediation decisions of hexavalent chromium in soils. In this study, we developed a microwave digestion-flame atomic absorption spectrometry method of hexavalent chromium in soils. By conducting the effect experiments of extraction agents, microwave digestion conditions, digestion solution filtration treatments, we optimized the conditions for extracting and determining hexavalent chromium in soils. The digestion solution was composed of 20 mL of alkaline extract, 100 mg of magnesium chloride, 0.2 mL of dipotassium hydrogen phosphate buffer solution. Microwave digestion was conducted three times. The digested solution was filtrated with medium speed quantitative filter paper, and pH values of the solution were adjusted to 7.0-8.0. Under the optimized conditions, the observed concentrations of certified standard samples of soil were all within the range of standard values, and the recoveries of soil matrix spiked ranged from 85.5% to 88.7%, with the relative standard deviations of 7.6%-8.0%. Compared to the standard method of Alkali Solution Extraction-Flame Atomic Absorption Spectrophotometry (HJ 1082-2019), the method established in this study is suitable for the determination of hexavalent chromium in a large number of soil samples. Microwave digestion technology not only has high extraction efficiency, but also is technically facile and popular in different levels of laboratories. The method of microwave digestion-flame atomic absorption spectrometry proposed in this study will provide technical support for the rapid and accurate determination of hexavalent chromium in soils.

     

    • FullText(HTML)
  • loading
    • References(46)
  • [1]
    冯明玉,韦黎华,胡清,等.固化/稳定化修复后场地中铬的环境行为和归趋:以我国中部某修复后场地为例[J].环境科学研究,2022,35(5):1131-1139. doi: 10.13198/j.issn.1001-6929.2022.03.01

    FENG M Y,WEI L H,HU Q,et al.Environmental behavior and fate of chromium in solidification/stabilization post-remediation sites:a case study of a remediation site in central China[J].Research of Environmental Sciences,2022,35(5):1131-1139. doi: 10.13198/j.issn.1001-6929.2022.03.01
    [2]
    TRAN H N,NGUYEN D T,LE G T,et al.Adsorption mechanism of hexavalent chromium onto layered double hydroxides-based adsorbents:a systematic in-depth review[J].Journal of Hazardous Materials,2019,373:258-270. doi: 10.1016/j.jhazmat.2019.03.018
    [3]
    ZHAO P D,ZHANG H,YU J,et al.Conditions for mutual conversion of Cr(Ⅲ) and Cr(Ⅵ) in aluminum chromium slag[J].Journal of Alloys and Compounds,2019,788:506-513. doi: 10.1016/j.jallcom.2019.02.093
    [4]
    DHAL B,THATOI H N,DAS N N,et al.Chemical and microbial remediation of hexavalent chromium from contaminated soil and mining/metallurgical solid waste:a review[J].Journal of Hazardous Materials,2013,250/251:272-291. doi: 10.1016/j.jhazmat.2013.01.048
    [5]
    孙芳,何广平,吴宏海,等.有机配体对膨润土负载纳米零价铁还原Cr(Ⅵ)的影响[J].环境科学研究,2011,24(4):461-466. doi: 10.13198/j.res.2011.04.101.sunf.015

    SUN F,HE G P,WU H H,et al.Influence of various organic ligands on the removal of Cr(Ⅵ) by bentonite-supported nanoscale zero-valent iron[J].Research of Environmental Sciences,2011,24(4):461-466. doi: 10.13198/j.res.2011.04.101.sunf.015
    [6]
    王婉华,陈丽红,方征,等.土壤铬(Ⅵ)对赤子爱胜蚓的生态毒性效应[J].环境科学研究,2013,26(6):653-657. doi: 10.13198/j.res.2013.06.74.wangwh.004

    WANG W H,CHEN L H,FANG Z,et al.Ecotoxicity of chromium (Ⅵ) to Eisenia fetida in soil[J].Research of Environmental Sciences,2013,26(6):653-657. doi: 10.13198/j.res.2013.06.74.wangwh.004
    [7]
    刘美丽,牛其建,俞洋洋,等.碳基材料负载纳米零价铁去除六价铬的研究进展[J].环境科学研究,2022,35(3):768-779. doi: 10.13198/j.issn.1001-6929.2021.07.13

    LIU M L,NIU Q J,YU Y Y,et al.Progress in removal of hexavalent chromium by carbon-based materials loaded with nano zero-valent iron[J].Research of Environmental Sciences,2022,35(3):768-779. doi: 10.13198/j.issn.1001-6929.2021.07.13
    [8]
    RAGER J E,SUH M,CHAPPELL G A,et al.Review of transcriptomic responses to hexavalent chromium exposure in lung cells supports a role of epigenetic mediators in carcinogenesis[J].Toxicology Letters,2019,305:40-50. doi: 10.1016/j.toxlet.2019.01.011
    [9]
    ZHAO Y,YAN J,LI A P,et al.Bone marrow mesenchymal stem cells could reduce the toxic effects of hexavalent chromium on the liver by decreasing endoplasmic reticulum stress-mediated apoptosis via SIRT1/HIF-1α signaling pathway in rats[J].Toxicology Letters,2019,310:31-38. doi: 10.1016/j.toxlet.2019.04.007
    [10]
    NOGUEIRA T A R,MELO W J,FONSECA I M,et al.Fractionation of Zn,Cd and Pb in a tropical soil after nine-year sewage sludge applications[J].Pedosphere,2010,20(5):545-556. doi: 10.1016/S1002-0160(10)60044-6
    [11]
    生态环境部,国家市场监督管理总局.土壤环境质量 建设用地土壤污染风险管控标准:GB 36600—2018[S].北京:中国标准出版社,2018.
    [12]
    生态环境部.土壤和沉积物的测定碱溶液提取:火焰原子吸收分光光度法:HJ 1082-2019[S].北京:中国环境出版集团,2019.
    [13]
    薛浩,孟凡生,王业耀,等.酸化-电动强化修复铬渣场地污染土壤[J].环境科学研究,2015,28(8):1317-1323. doi: 10.13198/j.issn.1001-6929.2015.08.20

    XUE H,MENG F S,WANG Y Y,et al.Remediation of chromium residue-contaminated soil by preacidification electrokinetic remediation[J].Research of Environmental Sciences,2015,28(8):1317-1323. doi: 10.13198/j.issn.1001-6929.2015.08.20
    [14]
    YOSHIZAKI S,TOMIDA T.Principle and process of heavy metal removal from sewage sludge[J].Environmental Science & Technology,2000,34(8):1572-1575.
    [15]
    BARTLETT R J,KIMBLE J M.Behavior of chromium in soils:Ⅱ.hexavalent forms[J].Journal of Environmental Quality,1976,5(4):383-386.
    [16]
    朱月珍.土壤中六价铬的吸附与还原[J].环境化学,1982,1(5):359-364.
    [17]
    ANDERSON R A.Chromium as an essential nutrient for humans[J].Regulatory Toxicology and Pharmacology,1997,26(1):S35-S41. doi: 10.1006/rtph.1997.1136
    [18]
    CHEN C P,JUANG K W,LIN T H,et al.Assessing the phytotoxicity of chromium in Cr(Ⅵ)-spiked soils by Cr speciation using XANES and resin extractable Cr(Ⅲ) and Cr(Ⅵ)[J].Plant and Soil,2010,334(1/2):299-309.
    [19]
    DING W X,STEWART D I,HUMPHREYS P N,et al.Role of an organic carbon-rich soil and Fe(Ⅲ) reduction in reducing the toxicity and environmental mobility of chromium(Ⅵ) at a COPR disposal site[J].Science of the Total Environment,2016,541:1191-1199. doi: 10.1016/j.scitotenv.2015.09.150
    [20]
    GARG U K,KAUR M P,GARG V K,et al.Removal of hexavalent chromium from aqueous solution by agricultural waste biomass[J].Journal of Hazardous Materials,2007,140(1/2):60-68.
    [21]
    DAI J,BECQUER T,HENRI ROUILLER J,et al.Heavy metal accumulation by two earthworm species and its relationship to total and DTPA-extractable metals in soils[J].Soil Biology and Biochemistry,2004,36(1):91-98. doi: 10.1016/j.soilbio.2003.09.001
    [22]
    曾静.土壤和沉积物中六价铬提取方法的改进[J].四川环境,2021,40(5):218-221. doi: 10.14034/j.cnki.schj.2021.05.033

    ZENG J.Method improvement of hexavalent chromium extraction from soil and sediment[J].Sichuan Environment,2021,40(5):218-221. doi: 10.14034/j.cnki.schj.2021.05.033
    [23]
    US EPA.Method 3060A-1996,alkaline digestion for hexavalent chromium[S].Washington DC:US Government Printing Office,1996.
    [24]
    冷远鹏,薛晓康,章明洪.土壤碱消解检测六价铬的铬还原问题及质控结果分析[J].安徽农业科学,2019,47(21):206-208. doi: 10.3969/j.issn.0517-6611.2019.21.062

    LENG Y P,XUE X K,ZHANG M H.Determination of chromium reduction of hexavalent chromium by soil alkaline digestion and analysis of quality control results[J].Journal of Anhui Agricultural Sciences,2019,47(21):206-208. doi: 10.3969/j.issn.0517-6611.2019.21.062
    [25]
    VITALE R J,MUSSOLINE G R,PETURA J C,et al.Hexavalent chromium extraction from soils:evaluation of an alkaline digestion method[J].Journal of Environmental Quality,1994,23(6):1249-1256.
    [26]
    JAMES B R,PETURA J C,VITALE R J,et al.Hexavalent chromium extraction from soils:a comparison of five methods[J].Environmental Science & Technology,1995,29(9):2377-2381.
    [27]
    梁娜.土壤六价铬的碱液提取和分析方法探究[J].绿色科技,2021,23(24):54-56. doi: 10.3969/j.issn.1674-9944.2021.24.015
    [28]
    SALIHU S O,BAKAR N K A.A simple method for chromium speciation analysis in contaminated water using APDC and a pre-heated glass tube followed by HPLC-PDA[J].Talanta,2018,181:401-409. doi: 10.1016/j.talanta.2018.01.041
    [29]
    US EPA.Method 218.6.de-termination of dissolved hexavalent chromium in drinking water,groundwater,and industrial wastewater effluents by ion chromatography Revision 3.3[S].Washington DC:US EPA,1991.
    [30]
    炼晓璐,魏洪敏,甄长伟,等.碱消解-火焰原子吸收光谱法测定土壤中六价铬[J].中国无机分析化学,2021,11(3):23-27. doi: 10.3969/j.issn.2095-1035.2021.03.005

    LIAN X L,WEI H M,ZHEN C W,et al.Determination of hexavalent chromium in soil by alkali digestion flame atomic absorption spectrometry[J].Chinese Journal of Inorganic Analytical Chemistry,2021,11(3):23-27. doi: 10.3969/j.issn.2095-1035.2021.03.005
    [31]
    秦婷,董宗凤,吕晓华,等.碱消解-电感耦合等离子体发射光谱(ICP-OES)法测定土壤中六价铬[J].中国无机分析化学,2019,9(6):10-13. doi: 10.3969/j.issn.2095-1035.2019.06.003

    QIN T,DONG Z F,LYU X H,et al.Determination of hexavalent chromium in soil by alkaline digestion-inductively coupled plasma optical emission spectrometry(ICP-OES)[J].Chinese Journal of Inorganic Analytical Chemistry,2019,9(6):10-13. doi: 10.3969/j.issn.2095-1035.2019.06.003
    [32]
    JIA X Y,GONG D R,XU B,et al.Development of a novel,fast,sensitive method for chromium speciation in wastewater based on an organic polymer as solid phase extraction material combined with HPLC-ICP-MS[J].Talanta,2016,147:155-161. doi: 10.1016/j.talanta.2015.09.047
    [33]
    VACCHINA V,de la CALLE I,SÉBY F.Cr(Ⅵ) speciation in foods by HPLC-ICP-MS:investigation of Cr(Ⅵ)/food interactions by size exclusion and Cr(Ⅵ) determination and stability by ion-exchange on-line separations[J].Analytical and Bioanalytical Chemistry,2015,407(13):3831-3839. doi: 10.1007/s00216-015-8616-3
    [34]
    CATALANI S,FOSTINELLI J,GILBERTI M E,et al.Application of a metal free high performance liquid chromatography with inductively coupled plasma mass spectrometry (HPLC-ICP-MS) for the determination of chromium species in drinking and tap water[J].International Journal of Mass Spectrometry,2015,387:31-37. doi: 10.1016/j.ijms.2015.06.015
    [35]
    HEITLAND P,BLOHM M,BREUER C,et al.Application of ICP-MS and HPLC-ICP-MS for diagnosis and therapy of a severe intoxication with hexavalent chromium and inorganic arsenic[J].Journal of Trace Elements in Medicine and Biology:Organ of the Society for Minerals and Trace Elements (GMS),2017,41:36-40. doi: 10.1016/j.jtemb.2017.02.008
    [36]
    LEESE E,MORTON J,GARDINER P H E,et al.Development of a method for the simultaneous detection of Cr(Ⅲ) and Cr(Ⅵ) in exhaled breath condensate samples using μLC-ICP-MS[J].Journal of Analytical Atomic Spectrometry,2016,31(4):924-933. doi: 10.1039/C5JA00436E
    [37]
    KOTAS J,STASICKA Z.Chromium occurrence in the environment and methods of its speciation[J].Environmental Pollution,2000,107(3):263-283. doi: 10.1016/S0269-7491(99)00168-2
    [38]
    ZATKA V J.Speciation of hexavalent chromium in welding fumes interference by air oxidation of chromium[J].American Industrial Hygiene Association Journal,1985,46(6):327-331. doi: 10.1080/15298668591394914
    [39]
    JAMES B R,BARTLETT R J.Behavior of chromium in soils:Ⅶ.adsorption and reduction of hexavalent forms[J].Journal of Environmental Quality,1983,12(2):177-181.
    [40]
    JAMES B R.Hexavalent chromium solubility and reduction in alkaline soils enriched with chromite ore processing residue[J].Journal of Environmental Quality,1994,23(2):227-233.
    [41]
    VU H C,DWIVEDI A D,le T T,et al.Magnetite graphene oxide encapsulated in alginate beads for enhanced adsorption of Cr(Ⅵ) and As(Ⅴ) from aqueous solutions:role of crosslinking metal cations in pH control[J].Chemical Engineering Journal,2017,307:220-229. doi: 10.1016/j.cej.2016.08.058
    [42]
    丁井井.Method 3060A:碱消解法提取六价铬的影响因素分析[J].标准科学,2021(4):119-124. doi: 10.3969/j.issn.1674-5698.2021.04.021

    DING J J.Method 3060A:analysis of the influencing factors of alkaline digestion for hexavalent chromium[J].Standard Science,2021(4):119-124. doi: 10.3969/j.issn.1674-5698.2021.04.021
    [43]
    姚江.水浴振荡碱消解-火焰原子吸收法测定土壤中六价铬[J].云南化工,2022,49(1):44-47. doi: 10.3969/j.issn.1004-275X.2022.01.14

    YAO J.Determination of hexavalent chromium in soil by water bath oscillating alkali digestion and flame atomic absorption method[J].Yunnan Chemical Industry,2022,49(1):44-47. doi: 10.3969/j.issn.1004-275X.2022.01.14
    [44]
    安茂国,赵庆令,谭现锋,等.化学还原-稳定化联合修复铬污染场地土壤的效果研究[J].岩矿测试,2019,38(2):204-211. doi: 10.15898/j.cnki.11-2131/td.201806040068

    AN M G,ZHAO Q L,TAN X F,et al.Research on the effect of chemical reduction-stabilization combined remediation of Cr-contaminated soil[J].Rock and Mineral Analysis,2019,38(2):204-211. doi: 10.15898/j.cnki.11-2131/td.201806040068
    [45]
    林海兰,谢沙,文卓琼,等.碱消解-火焰原子吸收法测定土壤和固体废物中六价铬[J].分析实验室,2017,36(2):198-202.

    LIN H L,XIE S,WEN Z Q,et al.Determination of chromium(Ⅵ) in soil and solid waste by alkaline digestion-flame atomic absorption spectrometry[J].Chinese Journal of Analysis Laboratory,2017,36(2):198-202.
    [46]
    张杰芳,闫玉乐,夏承莉,焦发存,张海侠.微波碱消解-电感耦合等离子体发射光谱法测定煤灰中的六价铬[J].岩矿测试,2017,36(1):46-51. doi: 10.15898/j.cnki.11-2131/td.2017.01.007

    ZHANG J F,YAN Y L,XIA C L,et al.Determination of Cr(Ⅵ) in coal ash by microwave alkaline digestion and inductively coupled plasma-optical emission spectrometry[J].Rock and Mineral Analysis,2017,36(1):46-51. doi: 10.15898/j.cnki.11-2131/td.2017.01.007
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(1)  / Tables(11)

    Get Citation
    PDF
    XML

    Article Metrics

    Article views (268) PDF downloads(65) Cited by()
    Proportional views
    Related

    Copyright © 2012《Research of Environmental Sciences》 editorial京ICP备05031605号-5

    Address：No.8 Dayang Square, Beiyuan, An Wai, Chaoyang District, BeijingPost Code：100012Tel：010-84915128Email：hjkxyj@vip.163.com

    Supported by: Beijing Renhe Information Technology Co., Ltd.    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return