Abstract:
Based on continuous observation data of near-surface ozone from 19 ambient air quality monitoring stations in Zibo City, Shandong Province from 2016 to 2019, the spatial-temporal characteristics of atmospheric O
3 were studied using Pearson correlation analysis and inverse distance weighting method. The results showed that: (1) From 2016 to 2019, the 90
th percentile of
ρ(O
3-8 h) (maximum 8 h concentration on O
3 day) in Zibo City was 184-203 μg/m
3, which is 1.15-1.27 times of the limit value of level Ⅱ (160 μg/m
3) in
National Ambient Air Quality Standards (GB 3095-2012). (2) The seasonal average of
ρ(O
3-8 h) was characterized by summer (155 μg/m
3) > spring (129 μg/m
3) > autumn (104 μg/m
3) > winter (60 μg/m
3). The monthly variation of
ρ(O
3-8 h) showed 'double peak' pattern, peaking in June (186 μg/m
3) and September (147 μg/m
3), respectively. The diurnal variations of O
3 showed a 'single peak' pattern, with the peak value of 117 μg/m
3 at around 14:00. (3) The spatial distribution of
ρ(O
3-8 h) showed 'low in south-north area and high in middle area' pattern, with a uniform trend in the regional. (4) The variation of precursors such as CO, NO, NO
2 and NO
x were negatively correlated with
ρ(O
3-8 h), but this correlation was weak in summer. Local pollutants at night in winter contributed more to O
x than in daytime. (5)
ρ(O
3-8 h)was significantly positively correlated with temperature and wind speed, and negatively correlated with humidity. High
ρ(O
3-8 h) was observed under southwesterly dominated wind. The results showed typical photochemical characteristics of O
3 in Zibo, and O
3 pollution gradually increased from 2016 to 2019.