Abstract:
Soil phosphorus (P) can be transformed into various forms during the continuous dry-wet cycles, which is a critical process of soil P release in the riparian zone of the Three Gorges Reservoir. Therefore, the purple alluvial soils were collected and incubated under the drying and flooding conditions to explore the transformation processes and rates of soil P forms in the riparian zone of the Three Gorges Reservoir. The soil P forms were analyzed using the modified Hedley phosphorus sequential fractionation method. During the drying period, the transformation rates of soil sodium hydrogen carbonate extraction organic P (NaHCO
3-Po) and sodium hydrate extraction inorganic P (NaOH-Pi) increased from -6.27, -1.78 mg/(kg·d) to -0.69, -0.21 mg/(kg·d), respectively, and the proportions of NaHCO
3-Po and NaOH-Pi content in ex-Residual-P decreased by 21.58% and 5.95%, respectively. Contrarily, the transformation rates of soil water-soluble P (H
2O-Pi) and sodium hydrogen carbonate extraction inorganic P (NaHCO
3-Pi) decreased from 2.07, 1.74 mg/(kg·d) to 0.43, 0.42 mg/(kg·d), respectively, and the proportions of H
2O-Pi and NaHCO
3-Pi content in ex-Residual-P increased by 13.50% and 13.41%, respectively. During the flooding period, the transformation rates of NaHCO
3-Pi, NaHCO
3-Po and soil sodium hydrate extraction organic P (NaOH-Po) increased from -1.84, -4.98 and -1.72 mg/(kg·d) to -0.26, -0.55 and -0.12 mg/(kg·d), respectively, and the proportions of NaHCO
3-Pi, NaHCO
3-Po and NaOH-Po content in ex-Residual-P decreased by 9.12%, 19.33% and 4.03%, respectively. However, the transformation rates of H
2O-Pi, NaOH-Pi and soil hydrochloric acid extraction P (HCl-Pi) decreased from 4.51, 2.00 and 0.47 mg/(kg·d) to 0.63, 0.22 and 0.05 mg/(kg·d), respectively, and the proportions of H
2O-Pi, NaOH-Pi and HCl-Pi content in ex-Residual-P increased by 28.83%, 2.46% and 1.18%, respectively. In conclusion, NaHCO
3-Po and NaOH-Pi tended to be transformed into H
2O-Pi and NaHCO
3-Pi during the drying period, while NaHCO
3-Pi, NaHCO
3-Po and NaOH-Po were mostly transformed into H
2O-Pi, NaOH-Pi and HCl-Pi during the flooding period. NaHCO
3-Po was the main source of H
2O-Pi in the riparian zone during both the drying and flooding periods. Therefore, under the conditions of rainwater leaching and flooding, the release of P from soil in the riparian zone to the Three Gorges Reservoir can be decreased effectively by NaHCO
3-Po reduction.