有机质对土壤中多环芳烃纵向迁移的影响

Effect of Organic Matter on Longitudinal Migration of Polycyclic Aromatic Hydrocarbons in Soil

  • 摘要: 为探讨多环芳烃(PAHs)在不同有机质梯度土壤中的纵向迁移机理,以山东省广泛分布的潮土、褐土和棕壤为研究对象,配成低有机质含量(17 g/kg)、中有机质含量(30 g/kg)、高有机质含量(45 g/kg)三种梯度的较清洁土,以柴油原液配成污染土壤,采用室内土柱淋滤试验,模拟自然条件下土壤中PAHs的纵向迁移,分析淋滤后较清洁土和污染土中PAHs的含量及组成. 结果表明:PAHs在潮土中更易向下迁移,褐土和棕壤无显著性差异(P>0.05). PAHs主要富集于较清洁土柱表层(69.10%~73.68%),随土柱深度增加,PAHs含量逐渐降低;在去离子水条件下淋滤,较清洁土中低环PAHs的迁移能力大于高环PAHs. 与低有机质条件相比,中有机质条件下PAHs的淋滤率降低了20.43%~32.41%,高有机质条件下降低了48.16%~58.05%. 研究显示,低环PAHs易向下迁移,高环PAHs则较难向下迁移,有机质会抑制土壤中PAHs的纵向迁移,有机质含量越高,对PAHs纵向迁移的抑制作用越强.

     

    Abstract: In to explore the longitudinal migration mechanism of polycyclic aromatic hydrocarbons (PAHs) in soils with different organic matter gradients, we used widely distributed fluvo-aquic soil, cinnamon soil and brown soil in Shandong Province as the research objects, prepared cleaner soils with low (17 g/kg), medium (30 g/kg) and high (45 g/kg) organic matter levels, and contaminated soils with original diesel fuel, and used indoor soil column leaching experiments to simulate the longitudinal migration of PAHs in soils under natural conditions, and analyzed the content and composition of PAHs in cleaner soils and contaminated soils after leaching. The results showed that PAHs were easier to migrate downward in fluvo-aquic soil, and there was no significant difference between cinnamon soil and brown soil (P>0.05). PAHs were mainly concentrated in the surface layer of clean soil column (69.10%-73.68%), and the content of PAHs decreased with the increase of soil column depth; the migration ability of PAHs in low ring PAHs was higher than that in clean soil under deionized water condition. Compared with low organic matter conditions, the leaching rate of PAHs was reduced by 20.43%-32.41% under medium organic matter conditions and by 48.16%-58.05% under high organic matter conditions. The study showed that low-ring PAHs are easy to migrate downward, while high-ring PAHs are more difficult to migrate downward, and organic matter will inhibit the longitudinal migration of PAHs in soil, and the higher the organic matter content, the stronger the inhibition effect on longitudinal migration of PAHs.

     

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