2020—2021年冬季长三角北部典型农业城市大气PM2.5及其组分特征和来源解析

Characteristics and Source Apportion of Atmospheric PM2.5 and Its Components in a Northern Typical Agricultural City of the Yangtze River Delta in Winter of 2020-2021

  • 摘要: 长三角地区空气质量在“十三五”期间得到了大幅改善,但是其北部地区大气环境形势依然严峻,尤其在冬季霾频发,成为长三角地区深入打赢蓝天保卫战的短板. 本研究以长三角北部典型农业城市−宿州市为研究对象,于2020年12月—2021年2月在宿州市环境监测站开展环境大气PM2.5手工样品采集和化学组分分析. 结果表明:2020年12月—2021年2月,宿州市冬季PM2.5浓度平均值为(80±31) μg/m3,49%的采样天数高出《环境空气质量标准》(GB 3095—2012)日均值二级标准(75 μg/m3). 水溶性无机离子浓度平均值为(38.6±24.8) μg/m3,占PM2.5的48%,其中二次离子浓度为(33.8±20.3) μg/m3,在PM2.5中占比达到42%;宿州市NH4+浓度相对较高,加强对本地农业源NH3排放强度的控制可能是降低宿州市离子浓度乃至PM2.5浓度的关键. 总碳(TC)、有机碳(OC)和元素碳(EC)浓度平均值分别为(19.0±7.3)、(16.3±6.2)和(2.7±1.2) μg/m3,OC和EC在PM2.5中的占比分别为17%和2.8%. 地壳元素和痕量无机元素浓度平均值分别为(8.5±7.8)和(0.23±0.11) μg/m3,在PM2.5中的占比分别为10.5%和0.3%. PMF源解析结果表明,宿州市冬季大气PM2.5主要来自交通源(22%)、燃烧源(21%)和二次无机粒子(21%),同时,还受到扬尘源(18%)、工业源(15%)和烟花爆竹燃放源(3%)的影响. 因此,在冬季PM2.5浓度较高的宿州市,应重点加强交通源、燃烧源和二次无机前体物(NOx、SO2和NH3)的排放监管,减少PM2.5的二次生成;此外,还应在春节烟花爆竹集中燃放期间加强“禁燃措施”的宣传力度和管控力度,助力环境空气质量进一步改善.

     

    Abstract: During the ‘13th Five Year Plan’ period, the overall air quality in the Yangtze River Delta (YRD) region improved, significantly. However, the atmospheric environment situation in the northern area of YRD is still severe. In addition, the frequently occurrence of haze in winter has become a weakness in winning the battle to protest the blue sky. This study focuses on a typical agricultural city in the northern part of YRD region. Local PM2.5 samples were collected manually at the Suzhou Environmental Protection Monitoring Station from December of 2020 to February of 2021, and the chemical components of the samples were analyzed. The results showed that the average PM2.5 concentration in winter was (80±31) μg/m3, and 49% of the sampling days exceeded the standard limit of level Ⅱ (75 μg/m3) of Ambient Air Quality Standards (GB 3095-2012). The seasonal average concentration of water-soluble inorganic ions was (38.6±24.8) μg/m3, accounting for 48% of PM2.5. The average concentration of secondary inorganic ions was (33.8±20.3) μg/m3, accounting for 42% of PM2.5. The average concentration of NH4+ in Suzhou was relatively high, and the emission intensity of NH3 from local agricultural sources may be the key to reducing ion and even PM2.5 concentrations in Suzhou. The seasonal average concentrations of total carbon, organic carbon (OC) and elemental carbon (EC) were (19.0±7.3), (16.3±6.2) and (2.7±1.2) μg/m3, respectively, and OC and EC accounted for 17% and 2.8% of PM2.5, respectively. The seasonal average concentrations of crustal elements and trace inorganic elements were (8.5±7.8) and (0.23±0.11) μg/m3, respectively, accounting for 10.5% and 0.3% of PM2.5, respectively. According to the PMF results, the local atmospheric PM2.5 mainly came from traffic (22%), combustion (21%) and secondary inorganic (21%) sources. In addition, it was also affected by dust (18%), industrial (15%) and fireworks burning (3%) sources. Therefore, it is necessary to strengthen the emission regulations of traffic sources, combustion sources, and secondary inorganic precursors (NOx, SO2 and NH3) to reduce the secondary generation of PM2.5. In addition, it is also essential to increase publicity and control efforts to forbid fireworks during the intensive fireworks period of the Spring Festival to further improve the ambient air quality.

     

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