济南市夏季一次典型臭氧重污染过程分析

Research on a Typical O3 Heavy Pollution Event in Summer in Jinan

  • 摘要: 为掌握济南市环境空气臭氧(O3)重污染发生特征,利用空气质量监测数据、气象观测和再分析资料,选取2022年5月31日—6月5日济南市一次典型O3重度污染过程,分析了其主要成因及关键影响因素。结果表明:①2022年5月31日—6月5日济南市O3日最大8 h滑动平均值(O3-8 h浓度)的平均值为218 μg/m3,其中6月2日O3-8 h浓度为287 μg/m3,空气质量状况达到重度污染水平。②污染过程期间,地面风速范围为0.9~2.3 m/s,以北风为主;相对湿度为29%~48%,日最高气温均超过34 ℃。在污染最严重的6月1—2日,大气垂直速度(ω)为−0.1~0.1 Pa/s,以弱下沉气流为主。③基于观测的模型(OBM)模拟表明,污染过程期间O3生成受VOCs控制,对烯烃和芳香烃的敏感性较高,相对增量反应活性(RIR)分别为0.31和0.19。降低20%烯烃和芳香烃浓度可使日间(05:00—18:00)O3生成速率分别降低6.4%、4.7%。④气流轨迹聚类分析显示,污染初期济南市以来自安徽省、河南省的气团输送为主,随着污染加重,则以东南方向的短距离气团输送为主。O3的潜在贡献源区集中在潍坊市、淄博市等地区,而济南市莱芜区对本地前体物NO2贡献最大。研究显示,高空脊+低空反气旋的配置提供了稳定的环流背景,近地面持续的弱北风叠加地形阻挡作用,以及垂直方向的下沉运动是影响O3重污染发生的关键环境因素;O3生成主要受VOCs控制,烯烃和芳香烃是影响O3生成的活性VOCs物种。因此,在不利的天气条件下,济南市需要特别重视对关键VOCs组分排放源的监管,加强与周边区域的联防联控,从而减少O3重污染的出现。

     

    Abstract: In order to understand the patterns of heavy ozone (O3) pollution weather in Jinan, this study analyzed a typical moderate-to-heavy O3 pollution event from May 31st to June 5th, 2022, using air quality data, meteorological observations, and reanalysis datasets to identify the main causes and key influencing factors. The results indicated that during this period, the average daily maximum 8-hour mean O3 concentration (O3-8 h) was 218 μg/m3. On June 2nd, the O3-8 h concentration was 287 μg/m3, corresponding to severe pollution levels. Ground wind speeds ranged from 0.9 to 2.3 m/s, predominantly from the north, with the relative humidity between 29% and 48%, and daily maximum temperatures consistently exceeding 34 ℃. During the peak pollution episode (June 1st-2nd), the vertical velocity (ω) ranged from −0.1 to 0.1 Pa/s, indicating weak subsidence. Observation-base model (OBM) simulations revealed that O3 formation was VOCs-limited, with alkenes and aromatics as key precursors were, showing relative incremental reactivity (RIP) values of 0.31 and 0.19, respectively. A 20% reduction in these VOCs species could lower daytime (05:00-18:00) O3 production rates by 6.4% and 4.7%. Airflow trajectory analysis revealed that at the initial stage, most air parcels originated from Anhui and Henan, while as pollution intensified, short-range transport from Linyi via Zibo became dominant. Potential source contribution analysis identified Weifang and Zibo as the main O3 source regions, while Laiwu District contributed most to the local NO2 in Jinan. The research found that an upper level ridge combined with a low-level anticyclone created a stable circulation pattern. The persistent weak northerly winds, topological obstruction, and vertical subsidence were key meteorological drivers of the event. O3 generation was mainly controlled by VOCs, and alkenes and aromatic hydrocarbons were the active species that affected O3 formation. Under the unfavorable meteorological conditions, it is necessary to pay special attention to the supervision of major VOC emission sources and strengthen joint prevention and control with the surrounding regions to mitigate heavy O3 pollution events in Jinan.

     

/

返回文章
返回