Abstract:
The activated carbon was used as catalyzer and the ammonia as reducer to study the factors affecting NO
x conversion efficiency,such as temperature, O
xygen content,SO
2 and H
2O,etc.The mechanism of the low-temperature selective catalytic reduction(SCR) of NO
x over activated carbon was studied with transient response technique.The results show that at the experimental condition,NO
x conversion efficiency gradually decreases with the increase of the temperature,and gradually increases with the increase of O
xygen content.But the conversion efficiency increases slowly when O
xygen content is more than 2.5%.This shows that the activated carbon has favorable low-temperature SCR activity.The adding of O
xygen could promote catalytic reduction of NO
x.The reduction rate could be enhanced by pre-O
xidizing NO to NO
2.The effect of the SO
2 was less in a short time,but the SCR activity decreased when the H
2O was added and the activated carbon was poisoned.The experiment indicated that the SCR was in the mechanism of Eley-Rideal,and the NH
3 adsorption is the controlling step of the whole process.