有机氯农药在海河干流水体和菹草中的浓度分布

Distribution of Organochlorine Pesticides in Water and Potamogeton crispus L. from the Haihe River

  • 摘要: 于2008年3月29日—5月25日对海河干流水体和菹草中的有机氯农药(OCPs)——六六六(HCHs)和滴滴涕(DDTs)的分布进行了采样调查. 结果表明,水体中ρ(HCHs)和ρ(DDTs)分别为3.95~20.15和6.88~35.23 ng/L,平均值为11.11和15.34 ng/L;菹草中w(HCHs)和w(DDTs)分别为2.17~7.82和1.40~22.80 ng/g,平均值分别为4.49和7.79 ng/g,菹草生长旺盛期的w(HCHs)和w(DDTs)最高,其变化主要受水体中ρ(HCHs)和ρ(DDTs)的影响;菹草生长旺盛期HCHs和DDTs的PCF值最高;菹草中HCHs的主要成分为γ-HCH,而水体中为β-HCH;DDT是水体和菹草中DDTs的主要成分,但菹草中DDT的相对含量明显低于水体,与水体相比,DDT在菹草中能进一步被降解,且以好氧降解为主.

     

    Abstract: Concentrations of organochlorine pesticides (OCPs), HCHs and DDTs in water and the aquatic plant Potamogeton crispus L. were investigated from 29 March to 25 May 2008 in the main stream of the Haihe River. The results showed that the concentrations of HCHs and DDTs were in the range of 3.95-20.15 ng/L (mean 11.11 ng/L) and 6.88-35.23 ng/L (mean 15.34 ng/L) in water, and 2.17-7.82 ng/g (mean 4.49 ng/g) and 1.40-22.80 ng/g (mean 7.79ng/g) in Potamogeton crispus L., respectively. Concentrations and PCF of HCHs and DDTs in Potamogeton crispus L. reached the highest value during the Potamogeton crispus L. blooming period, and concentrations of HCHs and DDTs in Potamogeton crispus L. were correlated significantly to those in water. γ-HCH was the dominant HCH isomer in Potamogeton crispus L., while β-HCH was the dominant form of HCHs in water. Among DDTs, DDT was the most dominant compound in both water and Potamogeton crispus L., though the percentage of DDT was significantly lower in Potamogeton crispus L. This revealed that further biodegradation of DDT occurred in Potamogeton crispus L. and mainly under aerobic conditions.

     

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