长株潭城市群秋季大气颗粒物及其重金属元素污染特征

Study on the Pollution Characteristics of Atmospheric Particles and Heavy Matals in Autumn in Chang-Zhu-Tan Metropolitan Area

  • 摘要: 为研究长株潭城市群大气颗粒物及典型元素污染特征,于2011年11月在长沙、株洲、湘潭三地采集TSP和PM10样品,同期在北京进行采样,以分析颗粒物及其中重金属元素(Cr、Cd、Hg、Pb和As)质量浓度的分布特征. 结果表明:秋季长沙、株洲、湘潭三地的ρ(TSP)均低于北京,背景点(长沙沙坪站)最低,为(110±48)μg/m3. 株洲ρ(PM10)与北京相近,略高于湘潭和长沙,但背景点ρ(PM10)仍为最低. ρ(PM10)/ρ(TSP)在70.26%~95.80%之间,平均值为85.90%. 长株潭城市群的ρ(Cr)、ρ(Hg)、ρ(As)、ρ(Cd)和ρ(Pb)在TSP中分别为37.7~60.7、0.2~1.5、22.7~92.0、4.2~36.8和142.9~508.3ng/m3,在PM10中相应分别为20.4~33.5、0.1~1.0、20.6~74.2、3.8~31.9和126.1~432.4ng/m3. 长株潭城市群各采样点Cd在TSP和PM10中的富集因子均最大,分别为475.8~4690.7和840.5~7489.8;其次为Hg、Pb和As;Cr的富集因子在TSP和PM10中分别为7.8~33.3和9.1~33.6,均为最小.

     

    Abstract: To understand the pollution characteristics of atmospheric particles and heavy metals in Chang-Zhu-Tan metropolitan area, TSP and PM10 samples were collected in Changsha, Zhuzhou and Xiangtan in November 2011. Sampling was also concurrently conducted in Beijing for comparison of the concentrations of TSP and PM10. The concentrations of heavy metals (Cr, Cd, Hg, Pb and As) in both TSP and PM10 samples were measured. Results showed that the average TSP concentrations in Changsha, Zhuzhou and Xiangtan were all less than that in Beijing, with the lowest concentration (110±48) μg/m3 in the background site (Shaping station, Changsha). The average concentration of PM10 in Zhuzhou was similar to that in Beijing, but slightly higher than those in Changsha and Xiangtan. The lowest concentration of PM10 also occurred in the background site, Shaping station of Changsha. The average ratio of ρ(PM10)/ρ(TSP) was 85.90%, ranging from 70.26% to 95.80%. Concerning heavy metals, the ρ(Cr), ρ(Hg), ρ(As), ρ(Cd) and ρ(Pb) were 37.7-60.7,0.2-1.5,2.7-92.0,4.2-36.8and 142.9-508.3ng/m3, respectively, in TSP samples, while they were 20.4-33.5,0.1-1.0,0.6-74.2,3.8-31.9and 126.1-432.4ng/m3, in PM10 samples, in Changsha, Zhuzhou and Xiangtan respectively. The enrichment factor of Cd was the highest (475.8-4690.7,0.5-7489.8in TSP and PM10), followed by Hg, Pb, and As, while that of Cr was the lowest (7.8-33.3,9.1-33.6in TSP and PM10) among heavy metals.

     

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