Abstract:
To understand the pollution characteristics of atmospheric particles and heavy metals in Chang-Zhu-Tan metropolitan area, TSP and PM
10 samples were collected in Changsha, Zhuzhou and Xiangtan in November 2011. Sampling was also concurrently conducted in Beijing for comparison of the concentrations of TSP and PM
10. The concentrations of heavy metals (Cr, Cd, Hg, Pb and As) in both TSP and PM
10 samples were measured. Results showed that the average TSP concentrations in Changsha, Zhuzhou and Xiangtan were all less than that in Beijing, with the lowest concentration (110±48) μg/m
3 in the background site (Shaping station, Changsha). The average concentration of PM
10 in Zhuzhou was similar to that in Beijing, but slightly higher than those in Changsha and Xiangtan. The lowest concentration of PM
10 also occurred in the background site, Shaping station of Changsha. The average ratio of ρ(PM
10)/ρ(TSP) was 85.90%, ranging from 70.26% to 95.80%. Concerning heavy metals, the ρ(Cr), ρ(Hg), ρ(As), ρ(Cd) and ρ(Pb) were 37.7-60.7,0.2-1.5,2.7-92.0,4.2-36.8and 142.9-508.3ng/m
3, respectively, in TSP samples, while they were 20.4-33.5,0.1-1.0,0.6-74.2,3.8-31.9and 126.1-432.4ng/m
3, in PM
10 samples, in Changsha, Zhuzhou and Xiangtan respectively. The enrichment factor of Cd was the highest (475.8-4690.7,0.5-7489.8in TSP and PM
10), followed by Hg, Pb, and As, while that of Cr was the lowest (7.8-33.3,9.1-33.6in TSP and PM
10) among heavy metals.