Abstract:
Being replaced by new products or abandoned because of low durability, an increasing number of electronic wastes in which the plastic content was approximately 20% in the scrap heap. Considering the polypropylene (PP) would seriously age as the main constitution of the outer casing, which leads to the decrease of mechanical performance without not much value in recycling and utilizing. In the essay, the recycling of waste PP became more qualified by enhancing its strength and toughness. We aimed at the polypropylene (PP) in outer casing of wasted washing-machine. The plastic polypropylene (PP) of waste washing machine shell was set as the research object. The toughness of PP decreased significantly because of the degradation during the process. The study focused on toughness modification of waste plastic aiming to improve the impact strength for its recyclability. Waste polypropylene (PP) was modified by polyolefine elastomer (POE) and styrene-butadiene-styrene block copolymer (SBS) to solve the problem of impact strength declined significantly. POE and SBS were blended with waste PP as toughening agents, while thermal property and mechanical properties of the waste PP were studied. The results showed that the toughness of the waste PP can be improved obviously when POE and SBS was added. The impact fracture process of the waste PP blended toughening agents changed from brittle fracture to ductile fracture with increasing elastomer content. When 16.7% elastomer was added, the impact strength of waste PP/POE and waste PP/SBS was improved 2.33times and 1.90times than new PP''s, respectively. In general, impact property of PP/POE can be improved accordingly. POE dispersed more evenly than SBS in waste PP, when 16.7% elastomer was added, melt flowing rate of the waste PP/POE was 17.4g/10min,which is greater than waste PP/SBS. POE dispersed more evenly than SBS in waste PP, impact property and melt flowing rate of the waste PP can be improved accordingly. However, the bending strength of waste PP should be improved in next research. Modified PP could be used for the production of plastics such as the cylinder in the washing machine, and it had reached the standard of impact property. However, it needs to be further studied in improving the tensile strength and bending strength; otherwise, it could not meet the requirements of actual production and provide to related enterprises some technical supports.